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§ data & tools · No. M 166
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§ materials · No. 166

Fe₆Li₂Mg₂O₁₆Sn₂

iron oxide ceramic · structural ceramic

Fe6Li2Mg2O16Sn2 is a iron oxide ceramic suitable as structural-ceramic. Color: amber-brown. Fired at 1100°C from 4 precursors (SnO2, MgCO3, Fe2O3). Workshop batch: 1000g at €28.04. Compressive strength ~100 MPa; estimated 0.79 kg CO₂/kg (+258% vs clay brick). Notable: visible absorber. Confidence: medium.

Rendered sample plate of Fe₆Li₂Mg₂O₁₆Sn₂
Fe₆Li₂Mg₂O₁₆Sn₂ · rendered sample plate, 85x85x29 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
clay brick
CO₂
258% higher than clay brick (0.79 vs 0.22 kg CO₂/kg; 3.6× higher)
energy
75% higher than clay brick (5.25 vs 3.00 MJ/kg; 1.8× higher)
compressive
100 MPa
density
4.77 g/cm³
crystal
hexagonal
band gap
2.06 eV
cost
€28.04/kg · €28.04 / 1000 g batch
confidence
medium (synthesis route)
potential
0.23 · env 0.00 · novel 0.46 · struct 0.30 · lineage 0.50 · supply 0.00
flags
visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

An iron-oxide ceramic with lithium, magnesium and tin substitutions, fired at 1100 °C into a dense 4.77 g/cm³ amber-brown body at 100 MPa of compression. The visible-absorber chemistry means the body takes daylight into itself rather than reflecting it — the surface becomes a selective heat collector. Architecturally this places the tile in the thermal-mass-adjacent register: south-facing absorber cladding on trombe-wall assemblies where the warm tone reads as architectural choice rather than technical necessity, hypocaust-style floor tile in naturally-ventilated studios, and thermal-storage plinth blocks for passive-solar pavilion walls. The lithium and tin substitutions tune the thermal conductivity a step above the parent iron-oxide ceramic, so the tile takes up heat faster and re-releases it over a slightly compressed evening cycle. Supplements insulation rather than replacing it. Substitutes for conventional dark-toned absorber coatings where a body-coloured ceramic is preferred to a painted or sprayed surface. The caveat is CO₂: embodied carbon runs two hundred and fifty-eight per cent above fired clay brick, the supply-chain score is zero, and the 1000 g batch with 5 kg ceiling allows slightly more generous specification than the rare-earth family but still well short of envelope-run scale. The warm amber tone has to earn its carbon back through specified daily thermal work.

Material character

The face carries a saturated amber-brown reading, the iron oxide dominant and the tin content lending a faint reflective warmth rather than lightening the body. At 4.77 g/cm³ in an 85×85×29 mm block the slab is firmly two-handed, close in weight to a fired structural brick of the same footprint but denser-ringing when tapped. Surface vitrified semi-matte from the 1100 °C fire, the iron content producing a uniform skin colour without the grain-legibility of under-fired terracotta. Edges cold-cut, the kerf showing the characteristic iron-oxide rust-brown in the fresh cut where the saw exposes the un-oxidised interior. A distinct warm-absorber cousin to the cool-grey thermal-mass heavy-oxide siblings, closer in visual register to a weathered adobe block than to a fired architectural brick of the same footprint.

recipe

Recipe

1000 g batch · peak 1100 °C
elementprecursorformulamasssafety
Feiron(III) oxide (red)Fe2O346.83 gsafe
Lilithium carbonateLi2CO37.22 gsafe
Mgmagnesium carbonateMgCO316.48 gsafe
Sntin(IV) oxideSnO229.46 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 6Ramp
  • 7Hold
watch for

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.