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§ data & tools · No. M 174
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§ materials · No. 174

Ca₆O₁₆Si₄V₂

calcium silicate · cement alternative

Ca6O16Si4V2 is a calcium silicate suitable as cement-alternative. Color: white-grey. Fired at 1100°C from 3 precursors (CaCO3, SiO2, V2O5). Workshop batch: 1000g at €28.29. Compressive strength ~50 MPa; estimated 0.68 kg CO₂/kg (-19% vs Portland cement). Notable: visible absorber. Confidence: high.

Rendered sample plate of Ca₆O₁₆Si₄V₂
Ca₆O₁₆Si₄V₂ · rendered sample plate, 85x85x44 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
portland cement
CO₂
18.7% lower than Portland cement (0.68 vs 0.83 kg CO₂/kg)
energy
18.2% lower than Portland cement (4.50 vs 5.50 MJ/kg)
compressive
50 MPa
density
3.12 g/cm³
crystal
monoclinic
band gap
2.19 eV
cost
€28.29/kg · €28.29 / 1000 g batch
confidence
high (synthesis route)
potential
0.46 · env 0.23 · novel 0.46 · struct 0.15 · lineage 0.70 · supply 1.00
flags
visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

This is a low-CO₂ calcium-silicate binder with vanadium-driven visible-absorber chemistry, 50 MPa of compression and a 19 per cent cut in embodied CO₂ against Portland cement. The compression figure places it in the binder-alternative register rather than the reinforced-structural one: thin prefab cladding panels, floor-topping screeds in retrofit, non-reinforced landscape walls, pavilion-scale garden rooms, and thermal-wall infills where the V-driven absorption turns the wall itself into a passive solar collector. Natural placements are south-facing thermal-wall infill blocks in passive-solar housing, warm-toned cladding panels on office and cultural buildings where the body's visible absorption does double service as a heat-collection layer, and floor-topping screeds in sunlit day-lit workshops. The visible-absorber behaviour adds a functional register on top of the carbon argument: not just a cleaner Portland, but a wall that works thermally. Against Portland cement the pouring and formwork logic stay familiar, so workshop workflows transfer directly. The caveat is thermal: firing happens at 1100 °C, so the kiln-free argument does not apply, and the CO₂ saving is delivered through chemistry rather than through ambient cure. High confidence and clean supply-chain and safety scores make the specification straightforward at pavilion and retrofit scale.

Material character

The slab reads a warm white-grey body with a subtle yellow-olive undertone from the vanadium content, distinct from the cooler neutral grey of the unadditived calcium-silicates. At 3.12 g/cm³ and 85×85×44 mm the piece sits comfortably for a two-hand lift, slightly denser than ordinary Portland concrete for the same volume. Skin finishes vitrified and glassy-matte from the 1100 °C fire, a tighter surface than ambient-cured concrete ever develops; edges cold-cut, kerf-whitened. Against Portland the tap-tone rings higher and cleaner, and the body under raking sun warms visibly — a hint of the absorber behaviour emerging as colour-depth rather than as temperature.

recipe

Recipe

1000 g batch · peak 1100 °C
elementprecursorformulamasssafety
Cacalcium carbonate / limestoneCaCO358.72 gsafe
Siquartz flour / silicaSiO223.5 gsafe
Vvanadium pentoxideV2O517.78 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 6Ramp
  • 7Hold
watch for

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.