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§ data & tools · No. M 189
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§ materials · No. 189

Fe₂O₁₂Sr₄TiW

perovskite ceramic · functional ceramic

Fe2O12Sr4Ti1W1 is a perovskite ceramic suitable as functional-ceramic. Color: amber-brown. Fired at 1300°C from 4 precursors (SrCO3, WO3, Fe2O3). Workshop batch: 200g at €23.51. Compressive strength ~100 MPa; estimated 0.97 kg CO₂/kg (+343% vs clay brick). Notable: visible absorber. Confidence: medium.

Rendered sample plate of Fe₂O₁₂Sr₄TiW
Fe₂O₁₂Sr₄TiW · rendered sample plate, 70x70x35 mm · Generative Matter V3 · not a photograph
forms at
1300 °C · extreme-fire
replaces
clay brick
CO₂
343% higher than clay brick (0.97 vs 0.22 kg CO₂/kg; 4.4× higher)
energy
117% higher than clay brick (6.50 vs 3.00 MJ/kg; 2.2× higher)
compressive
100 MPa
density
5.84 g/cm³
crystal
triclinic
band gap
1.82 eV
cost
€117.55/kg · €23.51 / 200 g batch
confidence
medium (synthesis route)
potential
0.22 · env 0.00 · novel 0.46 · struct 0.20 · lineage 0.50 · supply 0.00
flags
visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

A strontium-titanate-ferrite-tungstate perovskite with a visible-absorber face: the body takes in visible light as heat rather than reflecting it, so the slab becomes a selective solar-gain collector in a thin-section surface element. Natural placements are south-facing absorber-tile patches on thermal-mass walls in passive-solar architecture, small-area warm-toned cladding inserts on trombe walls, rooftop solar-gain patches beside skylights, and threshold plates on south-facing entry sequences where the amber-brown colour and the heat uptake are the architectural argument together. At 100 megapascals of compression the body is strictly a surface element — active coating, responsive cladding insert, absorber-tile patch — rather than a structural wall. The caveats compound severely. Embodied CO₂ runs 343 per cent higher than fired clay brick, the supply-chain score sits at zero, safety score drops to 0.65 (iron-tungstate firing releases fine particulates), and the extreme 1300 °C peak puts production into specialist-kiln territory only. Workshop batches cap at 500 g. Specification belongs entirely in the signature-insert register: one absorber-tile patch in a passive-solar facade, paid for by the coupled colour-plus-heat behaviour, never as a continuous cladding. Confidence on the capability remains medium pending architectural-scale verification of the absorber performance.

Material character

A rich amber-brown body at 5.84 g/cm³ in a 70×70×35 mm slab — the iron-tungstate signature, distinct from the cobalt-blue and chromium-green siblings elsewhere in the perovskite and iron-oxide groups. The slab firms two-handed, noticeably denser than the mid-range ceramics in this batch. Surface sits vitrified matte from the 1300 °C fire, with a slight metallic oxide sheen where the iron-rich phase concentrates at the skin. Edges cold-cut with diamond-kerf whitening. Fully opaque; under direct sunlight the visible-absorber face warms palpably within minutes of exposure. Against a plain strontium-titanate perovskite the iron and tungsten together drive the colour firmly into amber-brown territory rather than the cleaner blues of the base family.

recipe

Recipe

200 g batch · peak 1300 °C
elementprecursorformulamasssafety
Feiron(III) oxide (red)Fe2O315.04 gsafe
Srstrontium carbonateSrCO355.61 gsafe
Tititanium dioxide (rutile)TiO27.52 gsafe
Wtungsten trioxide (yellow)WO321.83 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.