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§ data & tools · No. M 135
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§ materials · No. 135

Fe₆Mn₂Na₆O₁₆

iron oxide ceramic · structural ceramic

Fe6Mn2Na6O16 is a iron oxide ceramic suitable as structural-ceramic. Color: purple-brown. Fired at 1100°C from 3 precursors (Na2CO3, Fe2O3, MnO2). Workshop batch: 1000g at €3.32. Compressive strength ~100 MPa; estimated 0.79 kg CO₂/kg (+258% vs clay brick). Notable: visible absorber. Confidence: high.

Rendered sample plate of Fe₆Mn₂Na₆O₁₆
Fe₆Mn₂Na₆O₁₆ · rendered sample plate, 85x85x34 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
clay brick
CO₂
258% higher than clay brick (0.79 vs 0.22 kg CO₂/kg; 3.6× higher)
energy
75% higher than clay brick (5.25 vs 3.00 MJ/kg; 1.8× higher)
compressive
100 MPa
density
4.04 g/cm³
crystal
trigonal
band gap
1.57 eV
cost
€3.32/kg · €3.32 / 1000 g batch
confidence
high (synthesis route)
potential
0.31 · env 0.00 · novel 0.46 · struct 0.30 · lineage 1.00 · supply 0.00
flags
visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

A sodium-iron-manganate structural ceramic fired at 1100 °C, 100 MPa of compression, and a deep purple-brown body that carries the visible-absorber chemistry of a manganese-iron oxide. At block and tile scale this belongs to structural masonry with a thermal intent: absorber-face bricks for south-facing garden walls, dark-toned cladding blocks for pavilion façades that gather solar gain rather than rejecting it, paving units for courtyards meant to warm under the day, and thick threshold tiles at orangery entries. Against clay brick the compression is higher but the embodied CO₂ runs 258 per cent higher, so this cannot be used as bulk masonry — it is the absorber face of a composite wall, a single course of dark skin against a lime-mortared clay body behind. The 1 kg workshop batch and €3.32 price open up enough production for a pavilion-scale demonstration wall, which is where this material earns its specification. The HIGH-confidence rating on the compression figure makes the load path legible. The caveat is supply-chain: the score sits at zero for this precursor mix, so procurement is a bespoke exercise and not a catalogue order.

Material character

A deep purple-brown face characteristic of high-manganese iron oxides — darker than a hematite-only body, cooler than a pure-manganate one, closer in tone to an oxidised basalt. At 4.04 g/cm³ and 85×85×34 mm the slab sits firm two-handed, heavier in hand than a fired clay tile of the same footprint but lighter than the zirconium-grade ceramics nearby. Surface carries the vitrified skin of a high-fire oxide, satin-matte with a faint metallic sheen where iron migrated to the outermost micron during fire. Edges cold-cut, the kerf powder red-brown. Against a plain hematite brick the body is darker, denser, and the ring under tap is higher and cleaner.

recipe

Recipe

1000 g batch · peak 1100 °C
elementprecursorformulamasssafety
Feiron(III) oxide (red)Fe2O349.34 gsafe
Mnmanganese dioxideMnO217.91 gmoderate
Nasodium carbonate / soda ashNa2CO332.75 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 6Ramp
  • 7Hold
watch for

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.