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§ data & tools · No. M 031
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§ materials · No. 031

K₂Mn₆S₆

sulfide polysulfide · sulfide low temp

K2Mn6S6 is a sulfide polysulfide suitable as sulfide low temp. Color: yellow-orange. Fired at 130°C from 3 precursors (MnO2, S, K2CO3). Workshop batch: 500g at €10.76. Compressive strength ~150 MPa; estimated 0.09 kg CO₂/kg (-89% vs Portland cement). Notable: forms without a kiln. Confidence: high.

Rendered sample plate of K₂Mn₆S₆
K₂Mn₆S₆ · rendered sample plate, 85x85x36 mm · Generative Matter V3 · not a photograph
forms at
130 °C · hotplate · no kiln
replaces
portland cement
CO₂
89.1% lower than Portland cement (0.09 vs 0.83 kg CO₂/kg)
energy
89.1% lower than Portland cement (0.60 vs 5.50 MJ/kg)
compressive
150 MPa
density
3.81 g/cm³
crystal
hexagonal
band gap
0.02 eV
cost
€21.52/kg · €10.76 / 500 g batch
confidence
high (synthesis route)
potential
0.74 · env 1.00 · novel 1.00 · struct 0.30 · lineage 0.70 · supply 0.27
flags
zero kiln: Forming happens without firing — the material cures through chemistry at ambient or hotplate temperature. At building scale this removes the kiln from the supply chain: on-site casting, regional workshops, cold-country fabrication all become available.

Architectural potential

A manganese-rich polysulphide cast at 130 °C with potassium as the network modifier — 150 MPa of compression, an eighty-nine-per-cent reduction in embodied CO₂ against Portland cement, and the broadest workshop reach in this sub-family at 2 kg maximum batch. The size ceiling opens up pavilion-floor tile, cast threshold plates, interior dado panels and dense-acoustic infill blocks for studio partition walls. Against cement the argument is displacement rather than supplementation: the same pouring logic, the same plywood formwork, none of the kiln. Natural placements are workshop-cast floor pavers for a rural cultural centre, cast inlay panels for a library bay, and compression-loaded block-work for a cold-country self-build where kiln fuel is simply unavailable. The HIGH-confidence rating on the 150 MPa figure makes this one of the more specifiable zero-kiln candidates across the atlas. The caveat is supply: the supply-chain score sits at 0.29 because manganese-sulphide precursor routes are thinly served outside the battery industry, so a project that specifies this binder commits to a dedicated supplier relationship and a procurement lead well beyond what a workshop-scale studio normally plans for.

Material character

A saturated yellow-orange face characteristic of the polysulphide family, held slightly cooler than the copper variants by the potassium flux. At 3.81 g/cm³ the 85×85×36 mm slab is firm two-handed — slightly less dense-feeling than the copper-heavy siblings but noticeably more massive than a fired clay tile of the same footprint. Surface mold-matte with the clean meniscus sheen of a polysulphide cast; edges as-cast, slightly sharp. A fine sulphur bloom crystallises unevenly across the face under cure, visible as a pale silver dusting at raking angles. Against a copper-manganese sibling the bloom is brighter and the body runs clearer yellow rather than brown-red.

recipe

Recipe

500 g batch · peak 130 °C
elementprecursorformulamasssafety
Kpotassium carbonate / potashK2CO320.95 gsafe
Mnmanganese dioxideMnO279.05 gmoderate
schedule
  • Pre-heatHotplate to 150 °C
  • MeltSulfur liquefies at 115 °C; full liquid at 130 °C
  • CastPour at 140–145 °C
  • SetRoom temperature 30 min (firm) → 24 h (full strength)
watch for

Zero-kiln process — 130 °C hotplate cast only

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.