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§ data & tools · No. M 169
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§ materials · No. 169

AlO₂₄Se₈VZr₂

heavy oxide ceramic · thermal mass ceramic

Al1O24Se8V1Zr2 is a heavy oxide ceramic suitable as thermal mass ceramic. Color: grey-blue. Fired at 1250°C from 4 precursors (Se, ZrO2, V2O5). Workshop batch: 200g at €8.82. Compressive strength ~300 MPa; estimated 0.94 kg CO₂/kg (+326% vs clay brick). Notable: visible absorber. Confidence: medium.

Rendered sample plate of AlO₂₄Se₈VZr₂
AlO₂₄Se₈VZr₂ · rendered sample plate, 85x85x38 mm · Generative Matter V3 · not a photograph
forms at
1250 °C · high-fire
replaces
clay brick
CO₂
326% higher than clay brick (0.94 vs 0.22 kg CO₂/kg; 4.3× higher)
energy
108% higher than clay brick (6.25 vs 3.00 MJ/kg; 2.1× higher)
compressive
300 MPa
density
3.61 g/cm³
crystal
triclinic
band gap
1.56 eV
cost
€44.10/kg · €8.82 / 200 g batch
confidence
medium (synthesis route)
potential
0.28 · env 0.00 · novel 0.46 · struct 0.60 · lineage 0.50 · supply 0.00
flags
visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

An aluminium-selenium-vanadium-zirconium heavy-oxide ceramic fired at 1250 °C, carrying an unusual 300 MPa of compression for its family and the visible-absorber flag. Three hundred megapascals lifts it out of the decorative register and into load-capable territory — a compressive performance a clay brick cannot approach, carried in a body designed to soak up solar gain rather than reflect it. The CO₂ runs more than four times that of clay brick, so the argument is thermal capture plus compression rather than environmental replacement. Natural placements are south-facing trombe-wall infill blocks where the grey-blue body is wanted as a visible thermal absorber, hypocaust floor-slab elements carrying passive solar heat into radiant release, thick thermal-mass courses in entry vestibules facing east or south, and bracket-stones in landscape architecture where compression and heat-battery behaviour are both desired. The 85×85×38 mm slab format and 500 g workshop ceiling keep specification at the single-element or small-run scale. The caveat is the selenium fraction: Se is both a supply-chain bottleneck (the score sits at zero) and a workshop-safety concern — peak firing has to happen in a well-ventilated kiln, with off-gas handling rather than open-air exhaust.

Material character

The slab reads a cool grey-blue with the muted mineral register of a heavy-oxide body rather than the saturated colour of a glass absorber. At 3.61 g/cm³ in an 85×85×38 mm format the piece takes a deliberate two-handed lift, noticeably lighter than the bismuth and tungsten siblings of the same family and closer to a fired stoneware paver in hand-feel. Surface vitrified matte from the 1250 °C fire; edges cold-cut, the kerf powder pale against the grey-blue body. A 1.56 eV absorption edge sits well below the visible band, so the body takes solar gain into itself in the expected visible-absorber way. Against the bismuth-yellow thermal-mass sibling the colour shift is complete.

recipe

Recipe

200 g batch · peak 1250 °C
elementprecursorformulamasssafety
Alcalcined aluminaAl2O35.0 gsafe
Seselenium (elemental)Se61.93 gmoderate
Vvanadium pentoxideV2O58.91 gmoderate
Zrzirconium dioxideZrO224.16 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.