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§ materials · No. 170

Ca₁₂Fe₈O₄₈Si₄Sn₈

heavy oxide ceramic · thermal mass ceramic

Ca12Fe8O48Si4Sn8 is a heavy oxide ceramic suitable as thermal mass ceramic. Color: amber-brown. Fired at 1250°C from 4 precursors (SnO2, CaCO3, Fe2O3). Workshop batch: 200g at €3.22. Compressive strength ~50 MPa; estimated 0.94 kg CO₂/kg (+326% vs clay brick). Notable: no special functions flagged. Confidence: medium.

Rendered sample plate of Ca₁₂Fe₈O₄₈Si₄Sn₈
Ca₁₂Fe₈O₄₈Si₄Sn₈ · rendered sample plate, 85x85x31 mm · Generative Matter V3 · not a photograph
forms at
1250 °C · high-fire
replaces
clay brick
CO₂
326% higher than clay brick (0.94 vs 0.22 kg CO₂/kg; 4.3× higher)
energy
108% higher than clay brick (6.25 vs 3.00 MJ/kg; 2.1× higher)
compressive
50 MPa
density
4.48 g/cm³
crystal
tetragonal
band gap
cost
€16.10/kg · €3.22 / 200 g batch
confidence
medium (synthesis route)
potential
0.24 · env 0.00 · novel 0.00 · struct 0.10 · lineage 0.80 · supply 0.70

Architectural potential

A calcium-iron-tin silicate in the thermal-mass register — the amber-brown iron-oxide content gives the body the warm register of terracotta while the tin content lifts its fired density into serious heat-storage territory. At 50 MPa of compression the material is not structural, so specification belongs to surface and infill work rather than load-bearing wall. Natural placements are thermal-wall infill tiles on south-facing elevations, amber-toned hypocaust floor patches in greenhouse and conservatory architecture, trombe-wall inlays where the warm iron-oxide face is a deliberate chromatic argument, and radiant-panel cladding in passive-solar pavilions. The amber-brown surface does architectural work that the neutral thermal-mass siblings cannot: it reads visually warm at all times, not only under solar gain, which matters in seasonal architecture where the visual cue of thermal presence supplements the physical performance. Against clay brick the embodied CO₂ runs four times higher, so specification has to be small-area and deliberate — a patch, a sill, a thermal band within a larger infill — not a whole wall. Workshop batch reaches 500 g, cost is €3.22 per 200 g, supply-chain score is 1.0 with commercially available precursors. The caveat is compression: 50 MPa forbids load-bearing placement, so the tile field must ride on a structural substrate rather than stand as its own wall.

Material character

An amber-brown body that reads unmistakably as an iron-oxide-rich fired ceramic — the tin content modifies the surface toward a slightly cooler, glassier finish than pure terracotta would carry, but the warm earth register dominates. At 4.481 g/cm³ and 85×85×31 mm the slab sits comfortably in the single-hand lift, close to a dense architectural floor tile in weight register. Surface reads vitrified matte with faint warm sheen, a tighter grain than unfluxed iron-oxide bodies and a fractionally higher surface sheen from the tin flux. Edges come cold-cut with a warm-dusted kerf. Rings slightly higher than an ordinary terracotta on the tap.

recipe

Recipe

200 g batch · peak 1250 °C
elementprecursorformulamasssafety
Cacalcium carbonate / limestoneCaCO336.55 gsafe
Feiron(III) oxide (red)Fe2O319.44 gsafe
Siquartz flour / silicaSiO27.31 gsafe
Sntin(IV) oxideSnO236.69 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.