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§ data & tools · No. M 085
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§ materials · No. 085

Bi₄Na₄O₁₆Si₄

alkali silicate glass · structural translucent glass

Bi4Na4O16Si4 is a alkali silicate glass suitable as structural translucent glass. Color: clear. Fired at 1150°C from 4 precursors (Bi2O3, SiO2, Na2CO3). Workshop batch: 400g at €14.80. Compressive strength ~500 MPa; estimated 0.84 kg CO₂/kg (-2% vs float glass). Notable: no special functions flagged. Confidence: high.

Rendered sample plate of Bi₄Na₄O₁₆Si₄
Bi₄Na₄O₁₆Si₄ · rendered sample plate, 70x70x38 mm · Generative Matter V3 · not a photograph
forms at
1150 °C · high-fire
replaces
float glass
CO₂
1.9% lower than float glass (0.84 vs 0.86 kg CO₂/kg)
energy
62.5% lower than float glass (5.62 vs 15.00 MJ/kg)
compressive
500 MPa
density
5.34 g/cm³
crystal
orthorhombic
band gap
3.36 eV
cost
€37.00/kg · €14.80 / 400 g batch
confidence
high (synthesis route)
potential
0.64 · env 0.78 · novel 0.00 · struct 1.00 · lineage 0.70 · supply 1.00

Architectural potential

A bismuth-sodium silicate glass fired at 1150 °C — a clear, load-bearing translucent at five hundred megapascals of compression, firmly in the walked-on and leaned-on register. Architectural placements are the classic structural-glass catalogue: stair treads with light coming up through the riser, floor panels in mezzanine galleries and public atria, transparent partitions that carry their own plane-load, pressed-glass beams in pavilions, and column-like light-admitting piers where the element both structures and illuminates. The energy overhead drops by sixty-two per cent against float glass because the bismuth flux lowers the melt viscosity, while embodied CO₂ is essentially unchanged — the substitution argument is thermal, not carbonaceous. Specify it where an integrated transparent load-path is wanted and where conventional steel-plus-glazing would separate structure from skin. A 400 g standard batch scales cleanly to five kilograms of workshop production, so slab-level tread runs and small glass beam elements are feasible without industrial casting. Still in the soda-silicate family, so annealing schedules and edge conditioning remain part of the detail. The caveat is cost and specification discipline: at €14.80 per 400 g the material is not bulk glazing, and bismuth's density lifts the slab's weight above ordinary float — every structural detail has to account for a heavier sheet than a glazier would expect.

Material character

The slab reads clear with a faint cool cast from sodium and the high bismuth content lifting the refractive register — distinctly more luminous in oblique light than an ordinary soda-lime pane, catching sharp internal reflections along the cold-cut edge. At 5.34 g/cm³ over 70×70×38 mm the piece is startlingly heavy for its clear body, sitting into the bench with a two-hand lift — a density-per-volume shift that the eye does not anticipate. Surface pressed-glass with the fine convex crown of a cast pane; edges cold-cut, lapidary-bloomed, ringing clean and long under a tap. A noticeably denser, slower-ringing body than a soda-lime sibling.

recipe

Recipe

400 g batch · peak 1150 °C
elementprecursorformulamasssafety
Bibismuth(III) oxide (yellow)Bi2O367.32 gmoderate
Nasodium carbonate / soda ashNa2CO315.31 gsafe
Siquartz flour / silicaSiO217.36 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 5Ramp
  • 6Hold

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.