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§ data & tools · No. M 179
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§ materials · No. 179

Ca₁₆O₄₈P₈Si₄Sr₄

calcium phosphate · bioceramic white

Ca16O48P8Si4Sr4 is a calcium phosphate suitable as bioceramic-white. Color: white. Fired at 1100°C from 4 precursors (CaCO3, Ca3(PO4)2, SrCO3). Workshop batch: 500g at €11.93. Compressive strength ~100 MPa; estimated 0.82 kg CO₂/kg (-1% vs Portland cement). Notable: bioactive. Confidence: medium.

Rendered sample plate of Ca₁₆O₄₈P₈Si₄Sr₄
Ca₁₆O₄₈P₈Si₄Sr₄ · rendered sample plate, 85x85x43 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
portland cement
CO₂
0.6% lower than Portland cement (0.82 vs 0.83 kg CO₂/kg)
energy
matches Portland cement (5.50 MJ/kg)
compressive
100 MPa
density
3.19 g/cm³
crystal
orthorhombic
band gap
cost
€23.86/kg · €11.93 / 500 g batch
confidence
medium (synthesis route)
potential
0.46 · env 0.01 · novel 0.80 · struct 0.20 · lineage 0.80 · supply 0.70
flags
bioactive: Actively hosts or supports biological activity on its surface. Bioreceptive cladding for moss and lichen, soil-contact interfaces that do not sterilise their neighbours, health-interior surfaces tuned for microbiome balance.

Architectural potential

A strontium-doped calcium phosphate-silicate tuned for the living-surface register — a bone- and tissue-compatible ceramic with an active surface that does not reject biological contact. The architectural argument sits on the living-surface potential: walls that host microflora, floors that support root anchors in interior planting, courtyard linings that invite colonisation rather than sterilising their edges, and healthcare interiors where the skin of the building is understood as a contact zone for the human microbiome rather than a chemical barrier. Natural placements are clinical-interior wall tiles in hospitals and operating-theatre support areas, bioreceptive cladding on north-facing walls in humid courtyards where moss and lichen are wanted, planter-linings in roof-gardens, and threshold plaques in healthcare architecture where the first touch wants to be tissue-friendly rather than antiseptic. Against Portland cement the embodied CO₂ is effectively flat and the firing energy matches exactly, so the environmental argument is neutral; the case for this material is biological rather than carbonaceous. The 100 MPa compression and two-kilogram workshop ceiling suit tile and panel-insert scale, not structural use. The caveat is fire discipline: 1100 °C peak keeps it in a ceramic-capable kiln, and the apatite-silicate chemistry needs a verified firing profile to preserve the bioactive surface — an under-fire or over-fire shifts the surface chemistry and kills the biological argument.

Material character

The 85×85×43 mm slab reads a clean bone-white with the faint pearl cast typical of a strontium-substituted apatite — a specific biological-ceramic signature, cooler than a calcium-only white and subtly warmer than a pure hydroxyapatite. Surface vitrified-matte from the 1100 °C fire with a microscopic porosity that reads as a slight velvet under raking light — the texture that hosts biological colonisation. Edges cold-cut, kerf-whitened. At 3.19 g/cm³ the slab lifts two-handed with a firm grip — close to a conventional stoneware tile register, lighter in hand than the denser rare-earth siblings and heavier than a porous terracotta of the same footprint. Rings bright and clean under a tap.

recipe

Recipe

500 g batch · peak 1100 °C
elementprecursorformulamasssafety
Cacalcium carbonate / limestoneCaCO343.6 gsafe
Ptricalcium phosphateCa3(PO4)233.78 gsafe
Siquartz flour / silicaSiO26.54 gsafe
Srstrontium carbonateSrCO316.08 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 5Ramp
  • 6Hold
watch for

Bioactive — biocompatible, antibacterial (Cu-doped silicocarnotite)

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.