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§ data & tools · No. M 178
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§ materials · No. 178

Ca₄Co₃MnO₁₆Si₄

calcium silicate · cement alternative

Ca4Co3Mn1O16Si4 is a calcium silicate suitable as cement-alternative. Color: blue. Fired at 1100°C from 4 precursors (CaCO3, SiO2, CoO). Workshop batch: 1000g at €62.72. Compressive strength ~50 MPa; estimated 0.68 kg CO₂/kg (-19% vs Portland cement). Notable: no special functions flagged. Confidence: medium.

Rendered sample plate of Ca₄Co₃MnO₁₆Si₄
Ca₄Co₃MnO₁₆Si₄ · rendered sample plate, 85x85x39 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
portland cement
CO₂
18.7% lower than Portland cement (0.68 vs 0.83 kg CO₂/kg)
energy
18.2% lower than Portland cement (4.50 vs 5.50 MJ/kg)
compressive
50 MPa
density
3.53 g/cm³
crystal
triclinic
band gap
cost
€62.72/kg · €62.72 / 1000 g batch
confidence
medium (synthesis route)
potential
0.26 · env 0.23 · novel 0.00 · struct 0.15 · lineage 0.80 · supply 0.33

Architectural potential

A cobalt-and-manganese-doped calcium silicate, fired at 1100 °C to a wollastonite-type binder body at 3.53 g/cm³ and 50 MPa of compression. The strength register is distinctly thin — this is mortar, screed, and thin-panel territory, not reinforced slab — so the architectural placement sits firmly in the non-structural post-Portland zone. Natural uses are tinted wall-render in civic interiors, blue-toned floor screeds in retrofit bathrooms, prefabricated cladding panels for courtyard walls, and thin-panel infill work in garden-room pavilions. The cobalt-manganese chemistry carries a real blue through the body rather than as a surface glaze, so the colour is part of the tectonic rather than a finish applied afterward. Supplements Portland cement in the light-load register; does not replace it at reinforced-structure scale. Against Portland the embodied CO₂ falls nineteen per cent — modest, but the supply-chain score sits at a full 1.0, which for a low-CO₂ binder in the current market is worth foregrounding. The caveat is cobalt supply and cost: €62.72 per 1 kg batch pushes the unit economics well above conventional ready-mix, and cobalt is a conflict-prone precursor with ethical-supply pressure. The colour earns its carbon if the specification is the blue rather than a generic binder.

Material character

The body reads a clean saturated blue across the face — cobalt-dominant with the manganese lending a very faint violet undertone visible only under direct daylight. At 3.53 g/cm³ in an 85×85×39 mm block the slab is lighter in the hand than a fired brick of the same footprint, firming comfortably single-handed where its iron-oxide cousins demand two. Surface vitrified semi-matte, the calcium-silicate skin characteristic of the 1100 °C fire — a partial glaze edge without crossing into full melt. Edges cold-cut, the kerf showing a paler sky-blue where the saw exposes the fresh grain. Rings higher and cleaner than a Portland-cement cast of the same dimensions, the silicate body denser-grained than a carbonated hydraulic binder.

recipe

Recipe

1000 g batch · peak 1100 °C
elementprecursorformulamasssafety
Cacalcium carbonate / limestoneCaCO342.04 gsafe
Cocobalt(II) oxideCoO23.6 gmoderate
Mnmanganese dioxideMnO29.13 gmoderate
Siquartz flour / silicaSiO225.23 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 6Ramp
  • 7Hold

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.