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§ data & tools · No. M 182
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§ materials · No. 182

Ca₄CoMn₃O₁₆Si₄

calcium silicate · cement alternative

Ca4Co1Mn3O16Si4 is a calcium silicate suitable as cement-alternative. Color: blue. Fired at 1100°C from 4 precursors (CaCO3, SiO2, CoO). Workshop batch: 1000g at €23.54. Compressive strength ~50 MPa; estimated 0.68 kg CO₂/kg (-19% vs Portland cement). Notable: no special functions flagged. Confidence: medium.

Rendered sample plate of Ca₄CoMn₃O₁₆Si₄
Ca₄CoMn₃O₁₆Si₄ · rendered sample plate, 85x85x41 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
portland cement
CO₂
18.7% lower than Portland cement (0.68 vs 0.83 kg CO₂/kg)
energy
18.2% lower than Portland cement (4.50 vs 5.50 MJ/kg)
compressive
50 MPa
density
3.42 g/cm³
crystal
triclinic
band gap
2.36 eV
cost
€23.54/kg · €23.54 / 1000 g batch
confidence
medium (synthesis route)
potential
0.31 · env 0.23 · novel 0.00 · struct 0.15 · lineage 0.80 · supply 0.65

Architectural potential

A cobalt-manganese fluxed calcium-silicate Portland replacement — the cobalt content drives a saturated blue body that no Portland-family concrete can match, and the 50 MPa compression register places specification at the non-structural panel and tile scale rather than at load-bearing block. Against Portland cement the embodied CO₂ drops by nineteen per cent, so the environmental argument is present but modest; the architectural argument is the colour. Natural placements are cobalt-blue cladding tiles for civic and sacred interiors, coloured floor screeds in retrofit contexts where the saturated pigment becomes the spatial signature, thin prefabricated panel cladding on pavilion walls, memorial-scale mortar work where the Chartres-blue register is wanted in cast-stone rather than in stained glass. The 1 kg standard batch and 5 kg workshop ceiling bring this to specifiable scale for single-building applications, and supply-chain score is 1.0. The caveat stack is real: €23.54 per kilogram is four times the cost of the aluminate sibling and an order of magnitude above Portland, the cobalt content shifts the dust-handling requirement into hazardous-material territory (safety score 0.65), and the 50 MPa compression means any floor-screed specification must ride on a structural substrate rather than carry its own load. Specification is deliberate, not default.

Material character

A deep saturated blue body that reads closer to a high-fired cobalt-pigmented stoneware than to a cement-family cast — the cobalt oxide drives the colour past the range of any ordinary concrete pigment. At 3.415 g/cm³ and 85×85×41 mm the slab sits in the single-hand lift for brief moves, two-hand for sustained handling, with a weight register close to a dense fired tile. Skin reads vitrified matte with a faint blue-sheened surface, finer than an unfluxed cement body would finish and edging toward partial surface glaze from the fluxing action. Edges cold-cut with a clean blue-dusted kerf. Rings brighter than Portland concrete on the tap.

recipe

Recipe

1000 g batch · peak 1100 °C
elementprecursorformulamasssafety
Cacalcium carbonate / limestoneCaCO341.0 gsafe
Cocobalt(II) oxideCoO7.67 gmoderate
Mnmanganese dioxideMnO226.71 gmoderate
Siquartz flour / silicaSiO224.61 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 6Ramp
  • 7Hold

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.