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§ data & tools · No. M 181
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§ materials · No. 181

O₂₀Sr₁₀TiV₄

perovskite ceramic · functional ceramic

O20Sr10Ti1V4 is a perovskite ceramic suitable as functional-ceramic. Color: grey-blue. Fired at 1300°C from 3 precursors (SrCO3, V2O5, TiO2). Workshop batch: 200g at €8.45. Compressive strength ~100 MPa; estimated 0.97 kg CO₂/kg (+343% vs clay brick). Notable: thermochromic VO2. Confidence: medium.

Rendered sample plate of O₂₀Sr₁₀TiV₄
O₂₀Sr₁₀TiV₄ · rendered sample plate, 85x85x28 mm · Generative Matter V3 · not a photograph
forms at
1300 °C · extreme-fire
replaces
clay brick
CO₂
343% higher than clay brick (0.97 vs 0.22 kg CO₂/kg; 4.4× higher)
energy
117% higher than clay brick (6.50 vs 3.00 MJ/kg; 2.2× higher)
compressive
100 MPa
density
4.92 g/cm³
crystal
tetragonal
band gap
0.62 eV
cost
€42.25/kg · €8.45 / 200 g batch
confidence
medium (synthesis route)
potential
0.33 · env 0.00 · novel 0.90 · struct 0.20 · lineage 0.50 · supply 0.00
flags
thermochromic VO2: Passive thermal-optical switching: transmission shifts near 68 °C without any driving signal. At building scale this gives a window that darkens as it heats, reducing solar gain without wiring or sensors.

Architectural potential

A strontium-vanadium perovskite fired at 1300 °C, carrying 100 MPa of compression and a vanadium-dioxide thermochromic layer. The CO₂ runs more than four times that of a fired clay brick and the extreme-fire peak adds to the energy bill, so any argument for its use has to be paid for by the chromism rather than by mass. Above 68 °C the vanadium site switches from semiconductor to metal and the body darkens; below it, the body clears again — a self-regulating solar-control tile without wiring, sensors or mechanical shading. Natural placements are small-area overlays on south-facing greenhouse and conservatory glazing, patch-scale tiles around skylight perimeters in atria to modulate hottest-hour gain, accent courses in double-skin façades, and ceiling-tile patterns in day-lit halls that shift register through the warming day. At 200 g per batch, specification sits at the signature-accent scale rather than the envelope scale. Against the V-doped perovskite sibling of the atlas the grey-blue resting colour is cooler and denser. The caveat is the CO₂ and energy ledger plus the supply-chain score at zero — vanadium availability and 1300 °C kiln logistics together forbid any use beyond the small patch or the signature element.

Material character

At room temperature the slab reads a deep grey-blue, cooler and more mineral than the V-titanate sibling of the atlas. A 0.62 eV absorption edge sits deep in the infrared, so the visible colour is carried by the titanate lattice rather than by the vanadium fraction itself. At 4.92 g/cm³ in an 85×85×28 mm format the slab is heavy for its thinness, resisting the single-handed lift. Surface vitrified matte from the 1300 °C fire; edges cold-cut with diamond-saw kerf powder. The room-temperature state is what the camera records; the post-transition darker state belongs in a heated companion shot taken above 68 °C.

recipe

Recipe

200 g batch · peak 1300 °C
elementprecursorformulamasssafety
Srstrontium carbonateSrCO376.89 gsafe
Tititanium dioxide (rutile)TiO24.16 gsafe
Vvanadium pentoxideV2O518.95 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

Thermochromic — VO₂ metal-insulator switch at ~68 °C

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.