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§ data & tools · No. M 199
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§ materials · No. 199

Ca₉CeOSi₆

calcium silicate · cement alternative

Ca9Ce1O1Si6 is a calcium silicate suitable as cement-alternative. Color: white-grey. Fired at 1100°C from 3 precursors (CaCO3, SiO2, CeO2). Workshop batch: 1000g at €11.74. Compressive strength ~50 MPa; estimated 0.68 kg CO₂/kg (-19% vs Portland cement). Notable: no special functions flagged. Confidence: high.

Rendered sample plate of Ca₉CeOSi₆
Ca₉CeOSi₆ · rendered sample plate, 85x85x52 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
portland cement
CO₂
18.7% lower than Portland cement (0.68 vs 0.83 kg CO₂/kg)
energy
18.2% lower than Portland cement (4.50 vs 5.50 MJ/kg)
compressive
50 MPa
density
2.67 g/cm³
crystal
monoclinic
band gap
0.02 eV
cost
€11.74/kg · €11.74 / 1000 g batch
confidence
high (synthesis route)
potential
0.35 · env 0.23 · novel 0.00 · struct 0.15 · lineage 0.70 · supply 1.00

Architectural potential

A cerium-doped calcium silicate fired at 1100 °C, 50 MPa at 2.67 g/cm³ — a plain white-grey post-Portland binder with no functional flags and an honest eighteen-per-cent cut in embodied CO₂ and energy against Portland cement. At 50 MPa the role is non-reinforced non-structural-topping: pavilion wall infills, landscape-wall blocks, floor screeds and toppings in retrofit work, and prefabricated cladding panels for light framed additions. The cement comparison carries the argument to a client with no colour premium — the pouring logic stays familiar, the formwork stays familiar, the binder itself shifts. A 1 kg workshop batch at €11.74 scales to a 5 kg ceiling, which begins to make panel-work realistic at the studio scale. Cerium in the matrix does quiet service: a slight UV-stability benefit over plain wollastonite and a small grain-refinement effect, neither promoted as a flagged innovation. Natural placements are garden-room plinths, thermal-wall infills in south-facing conservatories, and screeds in acoustic retrofits over timber sub-floors. The caveat is thermal: vitrification at 1100 °C means the kiln-free argument does not apply — this is a low-CO₂ cement, not an ambient binder — and a project has to be clear which trade it is making before it specifies the material into its structural drawings.

Material character

A clean neutral white-grey through the 52 mm depth, with only the faintest warm cast from the cerium fraction under daylight and a slight cream note where the slab meets raking light along the long edge. At 2.67 g/cm³ and 85×85×52 mm the slab sits two-handed on the bench, close in weight-register to a block of cured mortar of the same face and distinctly heavier than the cobalt-iron-foamed sibling from this same batch. The 1100 °C fire is just enough to drive a vitrified skin that edges toward a partial matte glaze without crossing into melt. Edges cold-cut, kerf powder-whitened. Fully opaque. Rings a slightly higher note than the flagship Ca4K4O18Si6 exemplar — same family, leaner flux register.

recipe

Recipe

1000 g batch · peak 1100 °C
elementprecursorformulamasssafety
Cacalcium carbonate / limestoneCaCO362.84 gsafe
Cecerium(IV) oxideCeO212.01 gsafe
Siquartz flour / silicaSiO225.15 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 6Ramp
  • 7Hold

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.