CrO₁₂Pr₅W
rare earth oxide · rare earth ceramicCr1O12Pr5W1 is a rare earth oxide suitable as rare earth ceramic. Color: green. Fired at 1200°C from 3 precursors (Pr6O11, WO3, Cr2O3). Workshop batch: 100g at €38.45. Compressive strength ~100 MPa; estimated 0.90 kg CO₂/kg (+309% vs clay brick). Notable: uv luminescent, electrochromic tungstate. Confidence: medium.

- forms at
- 1200 °C · high-fire
- replaces
- clay brick
- CO₂
- 309% higher than clay brick (0.90 vs 0.22 kg CO₂/kg; 4.1× higher)
- energy
- 100% higher than clay brick (6.00 vs 3.00 MJ/kg; 2.0× higher)
- compressive
- 100 MPa
- density
- 0.65 g/cm³
- crystal
- monoclinic
- band gap
- 2.32 eV
- cost
- €384.50/kg · €38.45 / 100 g batch
- confidence
- medium (synthesis route)
- potential
- 0.37 · env 0.00 · novel 1.00 · struct 0.20 · lineage 0.50 · supply 0.10
- flags
- uv luminescent: Converts invisible ultraviolet into visible light. Signage panels, low-energy wayfinding tiles, emergency markings that draw their illumination from daylight rather than mains power. electrochromic tungstate: A voltage-switchable optical chemistry. In thin-film form a small DC signal shifts transmission from clear to tinted blue, opening the door to dimmable glazing and responsive partitions that do not need mechanical shading.
Architectural potential
A praseodymium-chromium-tungsten oxide fired at 1200 °C — a rare-earth ceramic carrying two distinct functional chemistries at once: ultraviolet luminescence and electrochromic tungstate switching. The embodied CO₂ runs more than four times that of clay brick and compression sits at one hundred megapascals, so bulk or structural use is off the table; this is a signature-element material and its placements are small, specific and symbolic. Natural placements are dual-function signage tiles that read green under daylight and glow under ultraviolet excitation for emergency wayfinding in underground corridors and cinemas; dimmable ceiling inserts in exhibition cases where the same tile can switch transmission under a small DC signal and emit under a blacklight cue; accent patches in theatre foyers and club architecture where the UV behaviour is the entire point of the surface. Untested at building scale in production architecture. The 100 g workshop batch at €38.45 with a 300 g ceiling means each tile is a piece-by-piece commission. The caveat is double: praseodymium supply is scarce (supply-chain score near 0.14), and the two coupled chemistries — luminescent rare-earth and electrochromic tungstate — demand verification of how each holds up under repeated cycling before any architectural integration.
Material character
The body reads a saturated green, darker and more blue-shifted than a standard chromium-glazed ceramic — the praseodymium lifts the green toward a distinct apple-peel tone when daylight hits the surface. At 0.65 g/cm³ over 120×120×107 mm the slab is remarkably light for its size, registering a high-porosity sinter rather than a dense rare-earth body; it lifts two-handed with the unexpected ease of a fired aerated ceramic. Surface matte from the sinter, with a faint powdery bloom along one face; edges cold-cut. Under a 365 nm excitation source the slab turns chartreuse with a clear emission glow — the camera sees it immediately.
Recipe
100 g batch · peak 1200 °C| element | precursor | formula | mass | safety |
|---|---|---|---|---|
| Cr | chromium(III) oxide | Cr2O3 | 6.56 g | safe |
| Pr | praseodymium oxide | Pr6O11 | 73.44 g | moderate |
| W | tungsten trioxide (yellow) | WO3 | 20.0 g | moderate |
- 1Ramp
- 2Hold
- 3Ramp
- 4Ramp
- 5Hold
- 6Ramp
- 7Ramp
UV-luminescent — emits visible light under 365 nm UV
Electrochromic — color switches under applied voltage (thin-film chemistry)