lab-eds
§ data & tools · No. M 123
menu
§ materials · No. 123

CrO₁₂Pr₅W

rare earth oxide · rare earth ceramic

Cr1O12Pr5W1 is a rare earth oxide suitable as rare earth ceramic. Color: green. Fired at 1200°C from 3 precursors (Pr6O11, WO3, Cr2O3). Workshop batch: 100g at €38.45. Compressive strength ~100 MPa; estimated 0.90 kg CO₂/kg (+309% vs clay brick). Notable: uv luminescent, electrochromic tungstate. Confidence: medium.

Rendered sample plate of CrO₁₂Pr₅W
CrO₁₂Pr₅W · rendered sample plate, 120x120x107 mm · Generative Matter V3 · not a photograph
forms at
1200 °C · high-fire
replaces
clay brick
CO₂
309% higher than clay brick (0.90 vs 0.22 kg CO₂/kg; 4.1× higher)
energy
100% higher than clay brick (6.00 vs 3.00 MJ/kg; 2.0× higher)
compressive
100 MPa
density
0.65 g/cm³
crystal
monoclinic
band gap
2.32 eV
cost
€384.50/kg · €38.45 / 100 g batch
confidence
medium (synthesis route)
potential
0.37 · env 0.00 · novel 1.00 · struct 0.20 · lineage 0.50 · supply 0.10
flags
uv luminescent: Converts invisible ultraviolet into visible light. Signage panels, low-energy wayfinding tiles, emergency markings that draw their illumination from daylight rather than mains power. electrochromic tungstate: A voltage-switchable optical chemistry. In thin-film form a small DC signal shifts transmission from clear to tinted blue, opening the door to dimmable glazing and responsive partitions that do not need mechanical shading.

Architectural potential

A praseodymium-chromium-tungsten oxide fired at 1200 °C — a rare-earth ceramic carrying two distinct functional chemistries at once: ultraviolet luminescence and electrochromic tungstate switching. The embodied CO₂ runs more than four times that of clay brick and compression sits at one hundred megapascals, so bulk or structural use is off the table; this is a signature-element material and its placements are small, specific and symbolic. Natural placements are dual-function signage tiles that read green under daylight and glow under ultraviolet excitation for emergency wayfinding in underground corridors and cinemas; dimmable ceiling inserts in exhibition cases where the same tile can switch transmission under a small DC signal and emit under a blacklight cue; accent patches in theatre foyers and club architecture where the UV behaviour is the entire point of the surface. Untested at building scale in production architecture. The 100 g workshop batch at €38.45 with a 300 g ceiling means each tile is a piece-by-piece commission. The caveat is double: praseodymium supply is scarce (supply-chain score near 0.14), and the two coupled chemistries — luminescent rare-earth and electrochromic tungstate — demand verification of how each holds up under repeated cycling before any architectural integration.

Material character

The body reads a saturated green, darker and more blue-shifted than a standard chromium-glazed ceramic — the praseodymium lifts the green toward a distinct apple-peel tone when daylight hits the surface. At 0.65 g/cm³ over 120×120×107 mm the slab is remarkably light for its size, registering a high-porosity sinter rather than a dense rare-earth body; it lifts two-handed with the unexpected ease of a fired aerated ceramic. Surface matte from the sinter, with a faint powdery bloom along one face; edges cold-cut. Under a 365 nm excitation source the slab turns chartreuse with a clear emission glow — the camera sees it immediately.

recipe

Recipe

100 g batch · peak 1200 °C
elementprecursorformulamasssafety
Crchromium(III) oxideCr2O36.56 gsafe
Prpraseodymium oxidePr6O1173.44 gmoderate
Wtungsten trioxide (yellow)WO320.0 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

UV-luminescent — emits visible light under 365 nm UV

Electrochromic — color switches under applied voltage (thin-film chemistry)

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.