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§ data & tools · No. M 162
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§ materials · No. 162

Cr₃FeO₂₄W₄Y₄

heavy oxide ceramic · thermal mass ceramic

Cr3Fe1O24W4Y4 is a heavy oxide ceramic suitable as thermal mass ceramic. Color: green. Fired at 1250°C from 4 precursors (WO3, Y2O3, Cr2O3). Workshop batch: 200g at €46.36. Compressive strength ~100 MPa; estimated 0.94 kg CO₂/kg (+326% vs clay brick). Notable: electrochromic tungstate, visible absorber. Confidence: medium.

Rendered sample plate of Cr₃FeO₂₄W₄Y₄
Cr₃FeO₂₄W₄Y₄ · rendered sample plate, 70x70x31 mm · Generative Matter V3 · not a photograph
forms at
1250 °C · high-fire
replaces
clay brick
CO₂
326% higher than clay brick (0.94 vs 0.22 kg CO₂/kg; 4.3× higher)
energy
108% higher than clay brick (6.25 vs 3.00 MJ/kg; 2.1× higher)
compressive
100 MPa
density
6.48 g/cm³
crystal
triclinic
band gap
2.22 eV
cost
€231.80/kg · €46.36 / 200 g batch
confidence
medium (synthesis route)
potential
0.35 · env 0.00 · novel 1.00 · struct 0.20 · lineage 0.50 · supply 0.00
flags
electrochromic tungstate: A voltage-switchable optical chemistry. In thin-film form a small DC signal shifts transmission from clear to tinted blue, opening the door to dimmable glazing and responsive partitions that do not need mechanical shading. visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

This is a passive thermal-battery ceramic that doubles as a voltage-switchable optical layer — heavy oxide tungstate body that absorbs daytime solar gain and re-releases it after dark, while a DC signal shifts its transmission between clear and tinted states. Natural placements are south-facing thermal-wall patches in passive-solar housing, trombe-wall infill tiles in greenhouses and hybrid conservatories, responsive glazing inserts in double-skin façades, switchable partition panels in hospital and laboratory interiors where dimmable separation is wanted without mechanical shading, and atrium ceiling tiles that dim actively at solar peak. The visible-absorber chemistry makes the body itself into a warm-toned thermal collector, shifting the thermal day the way a trombe wall does. But the embodied CO₂ at plus 326 per cent against clay brick forbids any bulk use: this is signature-tile and cladding-patch register, not wall-volume ceramic. At 100 MPa of compression the material is non-load-bearing in any primary-structure sense. The caveat is supply-chain: tungsten-yttrium-chromium-iron sourcing sits at a score of 0.0 in the atlas, meaning every raw input is sensitive. 1250 °C firing and 200 g workshop batches keep this firmly in the responsive-tile register.

Material character

The slab carries a deep saturated green body, the chromium-tungstate register distinct from any cobalt or vanadium green in the glass family — closer to oxidised verdigris than to bottle glass. At 6.48 g/cm³ and 70×70×31 mm the piece is dense and cold in the hand, a two-hand grip despite the small face — denser than any of the perovskite siblings in the atlas. Skin finishes vitrified and matte from the 1250 °C fire; edges cold-cut, the diamond-saw powder left along the kerf. Fully opaque. Under applied voltage the body shifts darker at the visible wavelengths — a slow blue-grey transition the camera should record in two states.

recipe

Recipe

200 g batch · peak 1250 °C
elementprecursorformulamasssafety
Crchromium(III) oxideCr2O313.52 gsafe
Feiron(III) oxide (red)Fe2O34.73 gsafe
Wtungsten trioxide (yellow)WO354.98 gmoderate
Yyttrium oxideY2O326.77 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

Electrochromic — color switches under applied voltage (thin-film chemistry)

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.