Cr₃FeO₂₄W₄Y₄
heavy oxide ceramic · thermal mass ceramicCr3Fe1O24W4Y4 is a heavy oxide ceramic suitable as thermal mass ceramic. Color: green. Fired at 1250°C from 4 precursors (WO3, Y2O3, Cr2O3). Workshop batch: 200g at €46.36. Compressive strength ~100 MPa; estimated 0.94 kg CO₂/kg (+326% vs clay brick). Notable: electrochromic tungstate, visible absorber. Confidence: medium.

- forms at
- 1250 °C · high-fire
- replaces
- clay brick
- CO₂
- 326% higher than clay brick (0.94 vs 0.22 kg CO₂/kg; 4.3× higher)
- energy
- 108% higher than clay brick (6.25 vs 3.00 MJ/kg; 2.1× higher)
- compressive
- 100 MPa
- density
- 6.48 g/cm³
- crystal
- triclinic
- band gap
- 2.22 eV
- cost
- €231.80/kg · €46.36 / 200 g batch
- confidence
- medium (synthesis route)
- potential
- 0.35 · env 0.00 · novel 1.00 · struct 0.20 · lineage 0.50 · supply 0.00
- flags
- electrochromic tungstate: A voltage-switchable optical chemistry. In thin-film form a small DC signal shifts transmission from clear to tinted blue, opening the door to dimmable glazing and responsive partitions that do not need mechanical shading. visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.
Architectural potential
This is a passive thermal-battery ceramic that doubles as a voltage-switchable optical layer — heavy oxide tungstate body that absorbs daytime solar gain and re-releases it after dark, while a DC signal shifts its transmission between clear and tinted states. Natural placements are south-facing thermal-wall patches in passive-solar housing, trombe-wall infill tiles in greenhouses and hybrid conservatories, responsive glazing inserts in double-skin façades, switchable partition panels in hospital and laboratory interiors where dimmable separation is wanted without mechanical shading, and atrium ceiling tiles that dim actively at solar peak. The visible-absorber chemistry makes the body itself into a warm-toned thermal collector, shifting the thermal day the way a trombe wall does. But the embodied CO₂ at plus 326 per cent against clay brick forbids any bulk use: this is signature-tile and cladding-patch register, not wall-volume ceramic. At 100 MPa of compression the material is non-load-bearing in any primary-structure sense. The caveat is supply-chain: tungsten-yttrium-chromium-iron sourcing sits at a score of 0.0 in the atlas, meaning every raw input is sensitive. 1250 °C firing and 200 g workshop batches keep this firmly in the responsive-tile register.
Material character
The slab carries a deep saturated green body, the chromium-tungstate register distinct from any cobalt or vanadium green in the glass family — closer to oxidised verdigris than to bottle glass. At 6.48 g/cm³ and 70×70×31 mm the piece is dense and cold in the hand, a two-hand grip despite the small face — denser than any of the perovskite siblings in the atlas. Skin finishes vitrified and matte from the 1250 °C fire; edges cold-cut, the diamond-saw powder left along the kerf. Fully opaque. Under applied voltage the body shifts darker at the visible wavelengths — a slow blue-grey transition the camera should record in two states.
Recipe
200 g batch · peak 1250 °C| element | precursor | formula | mass | safety |
|---|---|---|---|---|
| Cr | chromium(III) oxide | Cr2O3 | 13.52 g | safe |
| Fe | iron(III) oxide (red) | Fe2O3 | 4.73 g | safe |
| W | tungsten trioxide (yellow) | WO3 | 54.98 g | moderate |
| Y | yttrium oxide | Y2O3 | 26.77 g | moderate |
- 1Ramp
- 2Hold
- 3Ramp
- 4Ramp
- 5Hold
- 6Ramp
- 7Ramp
Electrochromic — color switches under applied voltage (thin-film chemistry)
Visible absorber — saturated color from bandgap in the visible range