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§ data & tools · No. M 068
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§ materials · No. 068

Fe₂K₄O₈Si₂

alkali silicate glass · structural translucent glass

Fe2K4O8Si2 is a alkali silicate glass suitable as structural translucent glass. Color: amber-brown. Fired at 1150°C from 4 precursors (K2CO3, Fe2O3, SiO2). Workshop batch: 400g at €4.20. Compressive strength ~500 MPa; estimated 0.84 kg CO₂/kg (-2% vs float glass). Notable: visible absorber. Confidence: high.

Rendered sample plate of Fe₂K₄O₈Si₂
Fe₂K₄O₈Si₂ · rendered sample plate, 85x85x47 mm · Generative Matter V3 · not a photograph
forms at
1150 °C · high-fire
replaces
float glass
CO₂
1.9% lower than float glass (0.84 vs 0.86 kg CO₂/kg)
energy
62.5% lower than float glass (5.62 vs 15.00 MJ/kg)
compressive
500 MPa
density
2.94 g/cm³
crystal
orthorhombic
band gap
2.45 eV
cost
€10.50/kg · €4.20 / 400 g batch
confidence
high (synthesis route)
potential
0.75 · env 0.78 · novel 0.46 · struct 1.00 · lineage 0.70 · supply 1.00
flags
visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

An iron-doped alkali-silicate glass fired at 1150 °C, carrying 500 MPa of compression and the amber-brown body of a visible-light absorber. The structural reach places this in the load-bearing translucent register: pressed-glass floor panels, stair treads walked on from above, light-wells lined with coloured mass, and monolithic amber piers in public interiors. Against float glass the CO₂ is only two per cent lower but the energy is sixty-two per cent lower, so the environmental case rests on the fire rather than on the carbon balance. What the iron fraction adds is the selective absorption of visible light — the body takes solar gain into itself rather than passing it through, which makes the material a structural glazing element and a passive heat collector at the same time. Natural placements are south-facing trombe-wall infills cast as load-bearing blocks, amber glazing mullions in bathhouse and spa interiors, warm-toned thresholds in gallery architecture, and pressed-glass absorber panels in passive-solar schools. Against the clear and blue siblings in the same alkali-silicate run the architectural argument tilts toward thermal capture rather than clarity. The caveat is annealing: at 47 mm depth the cooling schedule is long and any short-cut produces internal stress visible as breakage under load.

Material character

The slab reads a deep amber-brown — a 2.45 eV absorption edge carried in solid section rather than as a thin tint. Held to daylight the 47 mm depth stains the view warm, closer to tobacco glass than to tea. At 2.94 g/cm³ in an 85×85×47 mm format the piece sits stably on the bench and wants a two-handed lift. Cold-cut edges carry the usual lapidary bloom; the pressed top face sits under a low crown with faint anneal striae close to the long edge. Against the cobalt-blue alkali-silicate sibling the colour shift is unmissable and the absorption-versus-transmission register entirely different.

recipe

Recipe

400 g batch · peak 1150 °C
elementprecursorformulamasssafety
Feiron(III) oxide (red)Fe2O328.71 gsafe
Kpotassium carbonate / potashK2CO349.69 gsafe
Siquartz flour / silicaSiO221.6 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 5Ramp
  • 6Hold
watch for

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.