lab-eds
§ data & tools · No. M 102
menu
§ materials · No. 102

Fe₂O₁₂Sr₄WZr

heavy oxide ceramic · thermal mass ceramic

Fe2O12Sr4W1Zr1 is a heavy oxide ceramic suitable as thermal mass ceramic. Color: amber-brown. Fired at 1250°C from 4 precursors (SrCO3, WO3, Fe2O3). Workshop batch: 200g at €23.86. Compressive strength ~300 MPa; estimated 0.94 kg CO₂/kg (+326% vs clay brick). Notable: electrochromic tungstate, magnetic ferrite, visible absorber. Confidence: medium.

Rendered sample plate of Fe₂O₁₂Sr₄WZr
Fe₂O₁₂Sr₄WZr · rendered sample plate, 70x70x35 mm · Generative Matter V3 · not a photograph
forms at
1250 °C · high-fire
replaces
clay brick
CO₂
326% higher than clay brick (0.94 vs 0.22 kg CO₂/kg; 4.3× higher)
energy
108% higher than clay brick (6.25 vs 3.00 MJ/kg; 2.1× higher)
compressive
300 MPa
density
5.85 g/cm³
crystal
triclinic
band gap
2.07 eV
cost
€119.30/kg · €23.86 / 200 g batch
confidence
medium (synthesis route)
potential
0.41 · env 0.00 · novel 1.00 · struct 0.60 · lineage 0.50 · supply 0.00
flags
electrochromic tungstate: A voltage-switchable optical chemistry. In thin-film form a small DC signal shifts transmission from clear to tinted blue, opening the door to dimmable glazing and responsive partitions that do not need mechanical shading. magnetic ferrite: Permanent-magnetic behaviour embedded in the material itself. Hardware-free fastening, mountable tile surfaces, reconfigurable partitions that hold by magnetism — a niche but specific tectonic opening. visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

A heavy iron-tungstate-zirconate ceramic whose 300 MPa compression and three stacked innovation behaviours carry a complex specification argument. As a passive thermal battery it belongs in south-facing thermal walls, hypocaust floor slabs, and trombe-wall infills — slow release of daytime solar gain after dark. The visible-absorber chemistry of the iron content means the amber-brown face takes solar radiation into itself rather than reflecting it, so the thermal performance and the colour are the same phenomenon. The tungsten content adds voltage-switchable tinting for chosen inserts, and the ferrite behaviour opens hardware-free tile mounting — reconfigurable wall surfaces held by embedded magnetism. Against fired clay brick the embodied-CO₂ balance is severe — 326 per cent higher — which forbids bulk use and places specification in the signature-insert register: a thermal-mass accent panel in an atrium, a switchable reveal at a south-facing window, a reconfigurable wall of magnetic tiles in a gallery. Cold-climate retrofit, solar-gain offices, and exhibition architecture are its natural territories. The caveat is scale and cost: €23.86 per 200 g batch with supply-chain score zero on tungsten-zirconium, a 1250 °C peak fire, and a 500 g workshop ceiling. This is a one-of-a-kind insert, not a wall system.

Material character

The slab carries a saturated amber-brown from the iron-tungstate matrix — warmer than the neutral tungstate-zincate sibling, the iron pulling the body toward the colour of weathered terracotta with a darker core reading. At 5.85 g/cm³ in a 70×70×35 mm piece, the body is dense and two-handed, noticeably heavier than an equivalent fired brick and closer in hand-feel to a cast iron-glaze tile. Skin matte from the sinter with a faint warm sheen; edges cold-cut, the diamond-kerf powder catching reddish in the cut. Fully opaque. A faint magnetism is legible at the corner if a small steel pin is brought close.

recipe

Recipe

200 g batch · peak 1250 °C
elementprecursorformulamasssafety
Feiron(III) oxide (red)Fe2O314.45 gsafe
Srstrontium carbonateSrCO353.43 gsafe
Wtungsten trioxide (yellow)WO320.98 gmoderate
Zrzirconium dioxideZrO211.15 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

Electrochromic — color switches under applied voltage (thin-film chemistry)

Magnetic — room-temperature magnetism from ferrite phase

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.