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§ data & tools · No. M 185
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§ materials · No. 185

Fe₃Li₇O₁₂Ti₂

iron oxide ceramic · structural ceramic

Fe3Li7O12Ti2 is a iron oxide ceramic suitable as structural-ceramic. Color: amber-brown. Fired at 1100°C from 3 precursors (Li2CO3, TiO2, Fe2O3). Workshop batch: 1000g at €51.91. Compressive strength ~100 MPa; estimated 0.79 kg CO₂/kg (+258% vs clay brick). Notable: visible absorber. Confidence: high.

Rendered sample plate of Fe₃Li₇O₁₂Ti₂
Fe₃Li₇O₁₂Ti₂ · rendered sample plate, 85x85x37 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
clay brick
CO₂
258% higher than clay brick (0.79 vs 0.22 kg CO₂/kg; 3.6× higher)
energy
75% higher than clay brick (5.25 vs 3.00 MJ/kg; 1.8× higher)
compressive
100 MPa
density
3.77 g/cm³
crystal
monoclinic
band gap
1.90 eV
cost
€51.91/kg · €51.91 / 1000 g batch
confidence
high (synthesis route)
potential
0.27 · env 0.00 · novel 0.46 · struct 0.30 · lineage 0.70 · supply 0.00
flags
visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

A lithium-iron-titanate ceramic fired at 1100 °C — the only load-bearing masonry candidate in this batch, with the iron content also giving it a visible-light absorber behaviour that opens a second argument for thermal-mass use. One hundred megapascals of compression is not primary-frame concrete territory but is comfortably above the traditional structural-brick envelope, so placements are block-work and structural tile in the same register as load-bearing masonry: extruded posts in garden-wall construction, thin-section compressive vaults in pavilion architecture, and structural tile infill in brick-grid façades. The visible-absorber chemistry adds a trombe-wall and thermal-mass argument: south-facing absorber panels where the iron-amber body takes solar gain into itself rather than reflecting it, warm-toned cladding on thermally-active walls, and hypocaust-style floor slabs where the colour doubles as the heat-capture logic. Embodied CO₂ runs nearly three and a half times that of clay brick, so the structural case has to be paid for by the thermal argument or the colour-and-fire-resistance combination. The 1000 g standard batch with a five-kilogram ceiling makes genuinely wall-scale production feasible. The caveat is cost: €51.91 per kilogram batch runs well above clay-brick economics, so the material belongs to signature thermal walls and architectural-statement masonry rather than general block-work.

Material character

The slab reads a warm amber-brown, the iron content sitting as a dissolved colourant that deepens with the 1100 °C fire — closer in tone to a terracotta brick than to a fired stoneware, but denser and more saturated. At 3.77 g/cm³ over 85×85×37 mm the piece is solid in the hand, lifting two-handed for its thickness and ringing clear and high under a tap. Surface vitrified matte with the characteristic skin of a fired iron-ceramic; edges cold-cut, kerf-whitened. Fully opaque. Against a standard clay-brick sibling the body reads darker, denser and noticeably warmer-toned, with a harder, longer ring under a tap.

recipe

Recipe

1000 g batch · peak 1100 °C
elementprecursorformulamasssafety
Feiron(III) oxide (red)Fe2O336.41 gsafe
Lilithium carbonateLi2CO339.31 gsafe
Tititanium dioxide (rutile)TiO224.28 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 6Ramp
  • 7Hold
watch for

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.