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§ data & tools · No. M 039
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§ materials · No. 039

Fe₄Mn₇Si₄V

metal pm only · sintered metal

Fe4Mn7Si4V1 is a metal pm only suitable as sintered-metal. Color: grey-blue. Fired at 1100°C from 3 precursors (Mn, Fe, Si). Workshop batch: 200g at €3.16. Compressive strength ~250 MPa; estimated 0.84 kg CO₂/kg (-53% vs structural steel). Notable: shape memory FeMnSi. Confidence: medium.

Rendered sample plate of Fe₄Mn₇Si₄V
Fe₄Mn₇Si₄V · rendered sample plate, 120x120x96 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
structural steel
CO₂
53.1% lower than structural steel (0.84 vs 1.80 kg CO₂/kg)
energy
74.4% lower than structural steel (5.62 vs 26.00 MJ/kg)
compressive
250 MPa
density
0.73 g/cm³
crystal
trigonal
band gap
0.00 eV
cost
€15.80/kg · €3.16 / 200 g batch
confidence
medium (synthesis route)
potential
0.61 · env 0.74 · novel 0.80 · struct 0.60 · lineage 0.20 · supply 0.46
flags
shape memory FeMnSi: Deforms on cue and snaps back to a remembered shape when warmed. Deployable canopies, self-tensioning fasteners, seismic-damping brackets, and geometry-changing envelopes all become mechanically possible.

Architectural potential

A vanadium-stabilised shape-memory sintered metal formed at 120×120×96 mm — a markedly larger format than its niobium sibling and a different architectural instrument because of it. The same FeMnSi shape-memory chemistry carries through, so the piece deforms on cue and snaps back when warmed, but at this block-scale it steps out of hardware and into the register of seismic-brace cores, self-resetting column-base connectors, and deployable-geometry hinges at primary-element size. Fifty-three per cent less embodied CO₂ than structural steel and a seventy-four-per-cent drop in firing energy make the environmental argument legible against conventional welded steelwork; the five-hundred-gram workshop ceiling means the block must be specified as a signature structural moment rather than a repeated detail. Natural placements are the bracket that holds a roof diaphragm and yields during a tremor, the column-base shoe in a retrofit of a masonry building in seismic country, and the reconfigurable connection in a demountable pavilion. The caveat is the density figure: at 0.727 g/cm³ the sintered body is porous and under-densified — a pressed green body or a lightweight variant, not a fully closed alloy — so the 250 MPa compressive strength should be read as upper-bound, with fatigue and creep behaviour verified before any seismic specification.

Material character

The 120×120×96 mm block reads a cool grey-blue with the faint warm undertone that vanadium brings to an iron-manganese sinter. Surface shows the coarse sintered grain characteristic of a pressed-metal green body — visible inter-particle porosity, matte throughout, with no mill finish. Edges are die-pressed with a generous radius and the parting line from the press tool still legible. At 0.727 g/cm³ the block lifts surprisingly easily for its size — lighter in hand than a clay brick of the same footprint, closer to a dense hardwood register than to a steel node. Rings low and muted under a tap, confirming an open-pore structure under the matte skin.

recipe

Recipe

200 g batch · peak 1100 °C
elementprecursorformulamasssafety
Feiron powder -325 meshFe31.01 gmoderate
Mnmanganese flakesMn53.39 gmoderate
Sisilicon granulesSi15.6 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 5Ramp
  • 6Ramp
  • 7END
watch for

Shape-memory — deformed body recovers on heating (Fe-Mn-Si)

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.