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§ data & tools · No. M 137
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§ materials · No. 137

Fe₄O₈SbV

iron oxide ceramic · structural ceramic

Fe4O8Sb1V1 is a iron oxide ceramic suitable as structural-ceramic. Color: amber-brown. Fired at 1100°C from 3 precursors (Sb2O3, V2O5, Fe2O3). Workshop batch: 1000g at €26.65. Compressive strength ~100 MPa; estimated 0.79 kg CO₂/kg (+258% vs clay brick). Notable: thermochromic VO2. Confidence: high.

Rendered sample plate of Fe₄O₈SbV
Fe₄O₈SbV · rendered sample plate, 70x70x40 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
clay brick
CO₂
258% higher than clay brick (0.79 vs 0.22 kg CO₂/kg; 3.6× higher)
energy
75% higher than clay brick (5.25 vs 3.00 MJ/kg; 1.8× higher)
compressive
100 MPa
density
5.12 g/cm³
crystal
monoclinic
band gap
0.96 eV
cost
€26.65/kg · €26.65 / 1000 g batch
confidence
high (synthesis route)
potential
0.38 · env 0.00 · novel 0.90 · struct 0.30 · lineage 0.70 · supply 0.00
flags
thermochromic VO2: Passive thermal-optical switching: transmission shifts near 68 °C without any driving signal. At building scale this gives a window that darkens as it heats, reducing solar gain without wiring or sensors.

Architectural potential

An iron-oxide ceramic with antimony and vanadium as functional modifiers, fired at 1100 °C to 100 MPa at 5.12 g/cm³, carrying a thermochromic vanadium-dioxide chemistry that flips the body's optical state at 68 °C. The load-bearing register is nominal at 100 MPa — this is not a block-work candidate — so the placements follow the thermochromic flag. Natural use is as a south-facing cladding tile on warm-toned brick façades where the body darkens visibly through the hottest afternoon hours and clears as evening cools, as a roof-tile insert over south-facing sun-rooms where summer over-heating is a live problem, and as a perimeter band around skylights in conservatories and double-skin façades that reads its own heat. Against clay brick the carbon trade is more than two-and-a-half-times negative, so the thermochromic capability has to earn the specification on its own — the building is buying self-regulation, not bulk. The amber-brown iron-oxide base colour suits warm brickwork and terracotta contexts rather than cool stone palettes. The caveat is supply: a supply-chain score of zero on antimony-vanadium-iron triples, 1100 °C peak, and a 1 kg batch-to-5 kg ceiling that allows a pattern band across a modest façade but not a full envelope.

Material character

Warm amber-brown through the 40 mm depth — iron-oxide matrix saturated to a terracotta register, with the faint tin-grey undertone that antimony brings into the matrix under shadow. At 5.12 g/cm³ and 70×70×40 mm the slab sits two-handed on the bench, denser than an ordinary fired-earthenware tile of the same face and closer in hand to a fired stoneware paver. Skin vitrified matte from the 1100 °C fire, edging into a partial glaze on the upper rim where the vanadium fraction concentrates during cooling. Edges cold-cut, kerf powder-ochre. Fully opaque. Above 68 °C the face shifts to a darker near-black state as the vanadium-dioxide transition completes — the photographic record wants the paired thermal shot alongside the ambient frame.

recipe

Recipe

1000 g batch · peak 1100 °C
elementprecursorformulamasssafety
Feiron(III) oxide (red)Fe2O357.43 gsafe
Sbantimony trioxideSb2O326.21 gmoderate
Vvanadium pentoxideV2O516.35 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 6Ramp
  • 7Hold
watch for

Thermochromic — VO₂ metal-insulator switch at ~68 °C

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.