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§ data & tools · No. M 194
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§ materials · No. 194

Fe₈Li₂O₁₆Sn₂

iron oxide ceramic · structural ceramic

Fe8Li2O16Sn2 is a iron oxide ceramic suitable as structural-ceramic. Color: amber-brown. Fired at 1100°C from 3 precursors (SnO2, Fe2O3, Li2CO3). Workshop batch: 1000g at €17.40. Compressive strength ~100 MPa; estimated 0.79 kg CO₂/kg (+258% vs clay brick). Notable: visible absorber. Confidence: high.

Rendered sample plate of Fe₈Li₂O₁₆Sn₂
Fe₈Li₂O₁₆Sn₂ · rendered sample plate, 70x70x41 mm · Generative Matter V3 · not a photograph
forms at
1100 °C · high-fire
replaces
clay brick
CO₂
258% higher than clay brick (0.79 vs 0.22 kg CO₂/kg; 3.6× higher)
energy
75% higher than clay brick (5.25 vs 3.00 MJ/kg; 1.8× higher)
compressive
100 MPa
density
5.03 g/cm³
crystal
hexagonal
band gap
1.60 eV
cost
€17.40/kg · €17.40 / 1000 g batch
confidence
high (synthesis route)
potential
0.27 · env 0.00 · novel 0.46 · struct 0.30 · lineage 0.70 · supply 0.00
flags
visible absorber: A real-colour solar-gain control layer. Where the body takes visible light into itself rather than reflecting it, the material becomes a selective heat collector — useful on thermal-mass walls, absorber panels, and warm-toned cladding.

Architectural potential

An iron-oxide structural ceramic in the load-bearing brick register, carrying a real-colour solar-absorber overlay that turns the wall itself into a thermal collector. At 100 MPa it sits below the flagship structural ceramics but well within the compressive band of a good fired brick, so block-work, extruded post and compressive-vault experiments are within reach. The visible-absorber chemistry is the architectural opening: the amber-brown face takes visible light into itself rather than reflecting it, warming the mass by several degrees above an insulated wall of the same envelope. Natural placements are south-facing thermal-mass walls in passive-solar houses where the absorber-plus-storage logic is built into the single element, rammed-earth-adjacent pavilion walls where the iron colour reads as geological, hypocaust-style floor slabs in gallery and chapel interiors, and trombe-wall infills where the warm tone is part of the visible surface rather than hidden behind a glazed cavity. Compression is enough for two- or three-storey masonry; beyond that, a reinforced frame takes over. The caveat is CO₂: 258 per cent above clay brick, which forbids bulk use and pushes specification to signature thermal-wall work rather than to repeated brick runs. Supply-chain score is zero on the tin-oxide content, which also limits scale; the material belongs in prototype passive-solar work.

Material character

The body reads a saturated amber-brown pulled from the iron-oxide matrix, warmer and more umber than a standard clay brick and darker along the solar-absorbing face — a deliberate heat-capturing tone, closer in register to a weathered cor-ten panel than to a standard fired brick. At 5.03 g/cm³ and 70×70×41 mm the slab handles with real structural-brick heft, a firm two-hand lift that reads closer to a dense terracotta than to ordinary fired clay. Surface finishes vitrified-matte from the 1100 °C fire, the iron-oxide skin slightly darker than the body underneath; edges cold-cut, kerf-whitened. The colour runs uniformly through the slab so cut edges read the same amber-brown as the face, useful for exposed-arris detailing.

recipe

Recipe

1000 g batch · peak 1100 °C
elementprecursorformulamasssafety
Feiron(III) oxide (red)Fe2O362.99 gsafe
Lilithium carbonateLi2CO37.29 gsafe
Sntin(IV) oxideSnO229.72 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 6Ramp
  • 7Hold
watch for

Visible absorber — saturated color from bandgap in the visible range

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.