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§ data & tools · No. M 052
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§ materials · No. 052

Fe₈Na₃S₈

sulfide polysulfide · sulfide low temp

Fe8Na3S8 is a sulfide polysulfide suitable as sulfide low temp. Color: yellow-orange. Fired at 130°C from 3 precursors (Fe2O3, S, Na2CO3). Workshop batch: 500g at €4.35. Compressive strength ~50 MPa; estimated 0.09 kg CO₂/kg (-89% vs Portland cement). Notable: forms without a kiln. Confidence: high.

Rendered sample plate of Fe₈Na₃S₈
Fe₈Na₃S₈ · rendered sample plate, 85x85x34 mm · Generative Matter V3 · not a photograph
forms at
130 °C · hotplate · no kiln
replaces
portland cement
CO₂
89.1% lower than Portland cement (0.09 vs 0.83 kg CO₂/kg)
energy
89.1% lower than Portland cement (0.60 vs 5.50 MJ/kg)
compressive
50 MPa
density
4.02 g/cm³
crystal
triclinic
band gap
cost
€8.70/kg · €4.35 / 500 g batch
confidence
high (synthesis route)
potential
0.77 · env 1.00 · novel 1.00 · struct 0.10 · lineage 0.70 · supply 0.68
flags
zero kiln: Forming happens without firing — the material cures through chemistry at ambient or hotplate temperature. At building scale this removes the kiln from the supply chain: on-site casting, regional workshops, cold-country fabrication all become available.

Architectural potential

A zero-kiln iron-sodium polysulfide cast at 130 °C, this material belongs firmly in the detail and surface register — inlays, specialty tiles, cast thresholds, decorative slab-work over timber substrates, and thick acoustic-wall insets. Fifty megapascals of compressive strength rules out load-bearing roles, but the chemistry-as-forming logic is the point: a body with cement-weight presence that leaves the kiln out of the supply chain entirely, poured in a warm studio from an iron-oxide, sulphur and soda-ash precursor stack. Against Portland cement, embodied CO₂ drops by eighty-nine per cent — the environmental argument is the dominant one. Natural placements are workshop-cast tiles in off-grid projects, warm-toned thresholds and sills in retrofit carpentry, cast inlays in gallery floors where the visitor reads the slab as a small geological event, and acoustic wall panels where mass without structural burden is wanted. The two-kilogram workshop ceiling keeps it at small-batch scale, so a whole-wall specification becomes a tiled composition rather than a poured monolith. The caveat is ventilation: saw-cutting and any warm re-working release sulphide odour, and the studio needs active extraction rather than an open window — fabrication culture sits closer to a chemistry bench than to a tile yard.

Material character

The 85×85×34 mm slab reads a saturated yellow-orange driven by the iron-sulfide matrix, with faint mustard striations where the sodium polysulfide phase has segregated on cooling. Surface is mold-matte with the meniscus sheen of a cast piece, slightly glossier in the cast basin than at the poured crown. Edges come as-cast, sharp and slightly reflective where the mold-release has polished them. At 4.02 g/cm³ the slab lifts single-handed but with a firm grip — distinctly heavier in hand than the manganese-copper sulfide sibling at the same thickness, and noticeably warmer-toned than the copper-red or the purple-manganese polysulfides elsewhere in the palette.

recipe

Recipe

500 g batch · peak 130 °C
elementprecursorformulamasssafety
Feiron(III) oxide (red)Fe2O380.07 gsafe
Nasodium carbonate / soda ashNa2CO319.93 gsafe
schedule
  • Pre-heatHotplate to 150 °C
  • MeltSulfur liquefies at 115 °C; full liquid at 130 °C
  • CastPour at 140–145 °C
  • SetRoom temperature 30 min (firm) → 24 h (full strength)
watch for

Zero-kiln process — 130 °C hotplate cast only

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.