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§ data & tools · No. M 147
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§ materials · No. 147

Gd₆O₁₄W₂

rare earth oxide · rare earth ceramic

Gd6O14W2 is a rare earth oxide suitable as rare earth ceramic. Color: neutral. Fired at 1200°C from 2 precursors (Gd2O3, WO3). Workshop batch: 100g at €47.48. Compressive strength ~100 MPa; estimated 0.90 kg CO₂/kg (+309% vs clay brick). Notable: uv luminescent, electrochromic tungstate. Confidence: medium.

Rendered sample plate of Gd₆O₁₄W₂
Gd₆O₁₄W₂ · rendered sample plate, 120x120x84 mm · Generative Matter V3 · not a photograph
forms at
1200 °C · high-fire
replaces
clay brick
CO₂
309% higher than clay brick (0.90 vs 0.22 kg CO₂/kg; 4.1× higher)
energy
100% higher than clay brick (6.00 vs 3.00 MJ/kg; 2.0× higher)
compressive
100 MPa
density
0.83 g/cm³
crystal
orthorhombic
band gap
2.28 eV
cost
€474.80/kg · €47.48 / 100 g batch
confidence
medium (synthesis route)
potential
0.37 · env 0.00 · novel 1.00 · struct 0.20 · lineage 0.50 · supply 0.10
flags
uv luminescent: Converts invisible ultraviolet into visible light. Signage panels, low-energy wayfinding tiles, emergency markings that draw their illumination from daylight rather than mains power. electrochromic tungstate: A voltage-switchable optical chemistry. In thin-film form a small DC signal shifts transmission from clear to tinted blue, opening the door to dimmable glazing and responsive partitions that do not need mechanical shading.

Architectural potential

A gadolinium-tungstate rare-earth ceramic fired at 1200 °C, carrying two distinct functional layers — ultraviolet-luminescence from the gadolinium host, and electrochromic tungstate switching from the W-O framework. At 100 MPa the compression supports signage-tile and accent-cladding use rather than structural placement. Natural placements are wayfinding panels in emergency-route lighting where a daytime UV charge delivers evening glow without mains supply, low-energy signage tiles in transit concourses, switchable accent panels in a permanent collection gallery where the tint state tracks exhibition lighting, and a responsive lighting tile in an intensive-care corridor that reads ambient light and returns it at night. At 309 per cent higher embodied CO₂ than clay brick, bulk use is excluded; this is a niche element justified entirely by the coupled luminescent-and-switchable behaviour. The caveat is severe: gadolinium supply is concentrated in a handful of refineries, the supply-chain score sits at 0.14, workshop batches cap at 100 g, and €47.48 per batch places specification at the level of a signature element or a small inset. The low bulk density (0.827 g/cm³) indicates an aerated cast — hand-feel is unexpectedly light for a rare-earth tile.

Material character

A neutral cool white body with a faint violet undertone from the gadolinium host — unsaturated at daylight, but with a legible glow signature when the UV channel is driven from below. At 0.827 g/cm³ the 120×120×84 mm block lifts almost one-handed, close in hand-feel to a dense softwood offcut rather than a conventional ceramic tile. Surface vitrified skin, satin-matte with a fine mottling from the tungstate phase at the outer micron. Edges cold-cut, kerf-powdered and chalky. Against an ordinary tungstate ceramic the body reads lighter in lift but denser in ring, and the low-voltage switched state shifts the face to a tinted blue-grey under sustained drive.

recipe

Recipe

100 g batch · peak 1200 °C
elementprecursorformulamasssafety
Gdgadolinium oxideGd2O370.11 gmoderate
Wtungsten trioxide (yellow)WO329.89 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

UV-luminescent — emits visible light under 365 nm UV

Electrochromic — color switches under applied voltage (thin-film chemistry)

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.