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§ data & tools · No. M 077
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§ materials · No. 077

K₂O₆WZr

heavy oxide ceramic · thermal mass ceramic

K2O6W1Zr1 is a heavy oxide ceramic suitable as thermal mass ceramic. Color: neutral. Fired at 1250°C from 3 precursors (WO3, K2CO3, ZrO2). Workshop batch: 200g at €45.25. Compressive strength ~300 MPa; estimated 0.94 kg CO₂/kg (+326% vs clay brick). Notable: electrochromic tungstate. Confidence: medium.

Rendered sample plate of K₂O₆WZr
K₂O₆WZr · rendered sample plate, 70x70x37 mm · Generative Matter V3 · not a photograph
forms at
1250 °C · high-fire
replaces
clay brick
CO₂
326% higher than clay brick (0.94 vs 0.22 kg CO₂/kg; 4.3× higher)
energy
108% higher than clay brick (6.25 vs 3.00 MJ/kg; 2.1× higher)
compressive
300 MPa
density
5.45 g/cm³
crystal
cubic
band gap
2.15 eV
cost
€226.25/kg · €45.25 / 200 g batch
confidence
medium (synthesis route)
potential
0.41 · env 0.00 · novel 1.00 · struct 0.60 · lineage 0.50 · supply 0.00
flags
electrochromic tungstate: A voltage-switchable optical chemistry. In thin-film form a small DC signal shifts transmission from clear to tinted blue, opening the door to dimmable glazing and responsive partitions that do not need mechanical shading.

Architectural potential

A tungsten-zirconium-potassium ceramic fired at 1250 °C into a dense heavy-oxide body, reaching 300 MPa of compression at 5.45 g/cm³. The tungsten content carries the material into the electrochromic register: under a small DC bias a thin tungstate film shifts from clear to deep blue, so the surface behaviour is switchable rather than passive. Architecturally this makes sense only at small-area overlay: switchable-tint window mullions in meeting-room partitions, voltage-dimmable glazing inserts for cinema foyers, reconfigurable privacy screens in medical consulting rooms. The 300 MPa body provides the thermal-mass register as well, so a south-facing thermal wall might carry electrochromic tiles at eye-level that darken through the afternoon as the ceramic mass behind them stores the solar gain. Supplements insulation and glazing rather than replacing them. The caveat is severe and has to be foregrounded: embodied CO₂ runs three hundred and twenty-six per cent above fired clay brick, the supply-chain score sits at zero, tungsten is a conflict-prone refractory, and €45.25 per 200 g batch with a 500 g ceiling keeps this firmly in the signature-patch register. The electrochromic chemistry has to earn its carbon back through daily switching, not through hiding behind other cladding.

Material character

Neutral pale-grey face with a barely-warm cast from the potassium flux; the tungsten content does not colour the body in its clear state but the density gives the slab a characteristic dead-heavy hand-feel. At 5.45 g/cm³ in a 70×70×37 mm block the piece is firmly two-handed, distinctly heavier than a clay brick of the same footprint. Surface vitrified semi-gloss from the 1250 °C peak, the potassium flux pushing the skin toward a partial glaze without crossing into full melt. Edges cold-cut, the kerf carrying the fine diamond-dust bloom. The switched state — deep electrochromic blue under DC bias — is not visible at rest; the slab reads pale-neutral until wired.

recipe

Recipe

200 g batch · peak 1250 °C
elementprecursorformulamasssafety
Kpotassium carbonate / potashK2CO328.02 gsafe
Wtungsten trioxide (yellow)WO347.0 gmoderate
Zrzirconium dioxideZrO224.98 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

Electrochromic — color switches under applied voltage (thin-film chemistry)

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.