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§ data & tools · No. M 002
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§ materials · No. 002

K₄O₂₃Si₈W₂

alkali silicate glass · structural translucent glass

K4O23Si8W2 is a alkali silicate glass suitable as structural translucent glass. Color: clear. Fired at 1150°C from 4 precursors (SiO2, WO3, K2CO3). Workshop batch: 400g at €68.11. Compressive strength ~500 MPa; estimated 0.84 kg CO₂/kg (-2% vs float glass). Notable: electrochromic tungstate. Confidence: high.

Rendered sample plate of K₄O₂₃Si₈W₂
K₄O₂₃Si₈W₂ · rendered sample plate, 85x85x42 mm · Generative Matter V3 · not a photograph
forms at
1150 °C · high-fire
replaces
float glass
CO₂
1.9% lower than float glass (0.84 vs 0.86 kg CO₂/kg)
energy
62.5% lower than float glass (5.62 vs 15.00 MJ/kg)
compressive
500 MPa
density
3.33 g/cm³
crystal
triclinic
band gap
3.36 eV
cost
€170.27/kg · €68.11 / 400 g batch
confidence
high (synthesis route)
potential
0.81 · env 0.78 · novel 1.00 · struct 1.00 · lineage 0.70 · supply 0.50
flags
electrochromic tungstate: A voltage-switchable optical chemistry. In thin-film form a small DC signal shifts transmission from clear to tinted blue, opening the door to dimmable glazing and responsive partitions that do not need mechanical shading.

Architectural potential

This composition is both a structural glass and a switchable glazing chemistry — the same recipe produces a load-bearing light-admitting solid at 42 mm thickness and, in thin-film form, a dimmable tinted layer driven by a small DC voltage. That pairing is the architectural argument: a single material class can handle a stair tread walked on from above, a window panel inserted into a curtain wall, and a switchable overlay inside an insulating glass unit. A light-well pier at the centre of an office floor could be specified from the bulk slab, while the electrochromic film rides on the outboard pane of the same assembly's vision glazing. Transparent partitions in meeting rooms gain on-demand privacy without mechanical blinds. Five hundred megapascals of compression plus a flat CO₂ balance against float glass — only two per cent over — means no carbon penalty, only a small densification penalty (3.33 g/cm³ instead of the 2.5 of soda-lime). The caveat is that the switching itself is a thin-film behaviour, not a bulk-slab one: bulk-specified, the slab is structural and clear; switching requires a separate thin-film deposition step at the glazing fabricator.

Material character

Bulk form reads nearly clear with a faint warm cast from the tungsten that shows most clearly when the slab sits against a pure-white ground. The top face carries a low convex crown and faint parallel anneal striae typical of pressed-glass cooling; cold-cut edges come powdery from the saw. At 3.33 g/cm³ the slab is perceptibly denser than ordinary window glass — a hand accustomed to 2.5-density float glass registers the difference immediately. The 42 mm depth reads fully transparent when backlit against the ambient grey, with only the warm tungsten cast distinguishing it from clear architectural glazing.

recipe

Recipe

400 g batch · peak 1150 °C
elementprecursorformulamasssafety
Kpotassium carbonate / potashK2CO322.64 gsafe
Siquartz flour / silicaSiO239.37 gsafe
Wtungsten trioxide (yellow)WO337.98 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Hold
  • 5Ramp
  • 6Hold
watch for

Electrochromic — color switches under applied voltage (thin-film chemistry)

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.