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§ data & tools · No. M 093
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§ materials · No. 093

Li₄O₁₆Si₄Sm₂Y₂

rare earth oxide · rare earth ceramic

Li4O16Si4Sm2Y2 is a rare earth oxide suitable as rare earth ceramic. Color: neutral. Fired at 1200°C from 4 precursors (Sm2O3, SiO2, Y2O3). Workshop batch: 100g at €18.34. Compressive strength ~500 MPa; estimated 0.90 kg CO₂/kg (+309% vs clay brick). Notable: uv luminescent. Confidence: medium.

Rendered sample plate of Li₄O₁₆Si₄Sm₂Y₂
Li₄O₁₆Si₄Sm₂Y₂ · rendered sample plate, 85x85x33 mm · Generative Matter V3 · not a photograph
forms at
1200 °C · high-fire
replaces
clay brick
CO₂
309% higher than clay brick (0.90 vs 0.22 kg CO₂/kg; 4.1× higher)
energy
100% higher than clay brick (6.00 vs 3.00 MJ/kg; 2.0× higher)
compressive
500 MPa
density
4.15 g/cm³
crystal
monoclinic
band gap
5.03 eV
cost
€183.40/kg · €18.34 / 100 g batch
confidence
medium (synthesis route)
potential
0.36 · env 0.00 · novel 0.50 · struct 1.00 · lineage 0.50 · supply 0.10
flags
uv luminescent: Converts invisible ultraviolet into visible light. Signage panels, low-energy wayfinding tiles, emergency markings that draw their illumination from daylight rather than mains power.

Architectural potential

A yttrium-samarium lithium silicate whose architectural argument is entirely carried by its luminescence: above daylight it reads a neutral sintered ceramic; under near-UV excitation it converts invisible ultraviolet into visible light and emits. At 500 MPa of compression the body could in principle carry load, but the CO₂ balance rules out bulk use — embodied carbon runs over four times that of a fired clay brick, so any specification has to pay for the emission with a functional role rather than a structural one. Natural placements are signage panels in public wayfinding systems that draw their illumination from ambient daylight UV, emergency-marking tiles in corridors and stair-cores, inset tread-edge markers in exhibition architecture, and accent cladding plaques at thresholds where a named moment is wanted. The 300 g workshop ceiling keeps the specification at plaque and patch scale rather than wall scale. The real caveat is double: samarium and yttrium sit inside the rare-earth supply bottleneck with a supply-chain score around 0.14, and €18.34 per 100 g is light-signalling cost, not cladding cost. Specify it the way one specifies a bronze dedication plaque — a single named location where the luminescent signal is the whole point of the piece.

Material character

The 85×85×33 mm slab reads a neutral cool white under daylight — the samarium-yttrium matrix has a very slight pinkish bloom only at direct grazing light. Under 365 nm excitation the face lifts into a pale peach-to-orange glow, the Sm³⁺ emission signature distinct from the blue-white of yttrium-only silicates. Surface vitrified matte from the 1200 °C fire; edges cold-cut with fine diamond-saw powder left in the kerf. At 4.15 g/cm³ the slab lifts two-handed — denser in hand than a clay brick of the same footprint, closer to a dense architectural stone, with a clean ceramic ring under the tap.

recipe

Recipe

100 g batch · peak 1200 °C
elementprecursorformulamasssafety
Lilithium carbonateLi2CO315.35 gsafe
Siquartz flour / silicaSiO224.96 gsafe
Smsamarium oxideSm2O336.23 gmoderate
Yyttrium oxideY2O323.46 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

UV-luminescent — emits visible light under 365 nm UV

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.