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§ data & tools · No. M 092
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§ materials · No. 092

Li₈O₁₀TeW

heavy oxide ceramic · thermal mass ceramic

Li8O10Te1W1 is a heavy oxide ceramic suitable as thermal mass ceramic. Color: neutral. Fired at 1250°C from 2 precursors (Li2CO3, WO3). Workshop batch: 200g at €45.30. Compressive strength ~100 MPa; estimated 0.94 kg CO₂/kg (+326% vs clay brick). Notable: electrochromic tungstate. Confidence: medium.

Rendered sample plate of Li₈O₁₀TeW
Li₈O₁₀TeW · rendered sample plate, 85x85x30 mm · Generative Matter V3 · not a photograph
forms at
1250 °C · high-fire
replaces
clay brick
CO₂
326% higher than clay brick (0.94 vs 0.22 kg CO₂/kg; 4.3× higher)
energy
108% higher than clay brick (6.25 vs 3.00 MJ/kg; 2.1× higher)
compressive
100 MPa
density
4.65 g/cm³
crystal
triclinic
band gap
3.44 eV
cost
€226.50/kg · €45.30 / 200 g batch
confidence
medium (synthesis route)
potential
0.35 · env 0.00 · novel 1.00 · struct 0.20 · lineage 0.50 · supply 0.00
flags
electrochromic tungstate: A voltage-switchable optical chemistry. In thin-film form a small DC signal shifts transmission from clear to tinted blue, opening the door to dimmable glazing and responsive partitions that do not need mechanical shading.

Architectural potential

A lithium-heavy tungstate-tellurate ceramic fired to 1250 °C, reaching only 100 MPa of compression — a distinctly lighter structural envelope than the potassium-zirconium sibling. At 4.65 g/cm³ the body is less dense too, so the thermal-mass argument weakens, but the electrochromic tungstate chemistry survives intact. The natural architectural place is non-load-bearing switchable-tint surface: hospital ward partition inserts where privacy switches on demand, reconfigurable library-carrel screens that tint during focussed work, and retail fitting-room wall panels that shift opacity without mechanical blinds. The lithium content pushes the optical response toward a cleaner clear-to-blue transition with less haze in the intermediate state, which matters where visible contrast between tinted and untinted regions is the architectural register. Supplements conventional glazing rather than replacing it. The caveat is stark: embodied CO₂ runs three hundred and twenty-six per cent above fired clay brick, the supply-chain score sits at zero, tellurium is a scarce by-product of copper refining, and €45.30 per 200 g batch puts any use into the bespoke-signage register. Lithium mobility at the tungstate surface also means the switching chemistry degrades over time; the specification has to budget for tile replacement on a ten-year cycle.

Material character

The slab reads a pale neutral white-grey, warmer than the zirconium-variant sibling thanks to the lithium-tellurate matrix softening the body. At 4.65 g/cm³ in an 85×85×30 mm format the piece is larger-footprint but actually lighter in the hand than the smaller K-W-Zr variant from the same family — the lithium substitution drops the density noticeably. Surface vitrified glossier than the potassium sibling, the tellurium lending a faint pearl-sheen that catches shadow under raking light; edges cold-cut, kerf-bright. Rings higher and longer than its denser sibling when tapped, the lithium content lightening the acoustic body. The tinted electrochromic state is invisible in the at-rest sample.

recipe

Recipe

200 g batch · peak 1250 °C
elementprecursorformulamasssafety
Lilithium carbonateLi2CO356.04 gsafe
Wtungsten trioxide (yellow)WO343.96 gmoderate
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

Electrochromic — color switches under applied voltage (thin-film chemistry)

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.