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§ data & tools · No. M 074
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§ materials · No. 074

O₂PrSm₅Sn₆Zr₄

heavy oxide ceramic · thermal mass ceramic

O2Pr1Sm5Sn6Zr4 is a heavy oxide ceramic suitable as thermal mass ceramic. Color: neutral. Fired at 1250°C from 4 precursors (SnO2, Sm2O3, ZrO2). Workshop batch: 200g at €47.30. Compressive strength ~300 MPa; estimated 0.94 kg CO₂/kg (+326% vs clay brick). Notable: uv luminescent. Confidence: medium.

Rendered sample plate of O₂PrSm₅Sn₆Zr₄
O₂PrSm₅Sn₆Zr₄ · rendered sample plate, 70x70x26 mm · Generative Matter V3 · not a photograph
forms at
1250 °C · high-fire
replaces
clay brick
CO₂
326% higher than clay brick (0.94 vs 0.22 kg CO₂/kg; 4.3× higher)
energy
108% higher than clay brick (6.25 vs 3.00 MJ/kg; 2.1× higher)
compressive
300 MPa
density
7.86 g/cm³
crystal
orthorhombic
band gap
inf eV
cost
€236.50/kg · €47.30 / 200 g batch
confidence
medium (synthesis route)
potential
0.30 · env 0.00 · novel 0.50 · struct 0.60 · lineage 0.50 · supply 0.10
flags
uv luminescent: Converts invisible ultraviolet into visible light. Signage panels, low-energy wayfinding tiles, emergency markings that draw their illumination from daylight rather than mains power.

Architectural potential

A heavy zirconate-stannate thermal battery with a UV-luminescent twist: samarium and praseodymium together emit in the visible range when excited at 365 nm, so the same slab that stores daytime heat also signals under targeted UV at night. Natural placements are south-facing thermal walls in atria and conservatories where the slow thermal day is the argument and the evening glow is a ritual accent; hypocaust-style floor slabs in gallery piers with integrated UV emitters under plinths; night-flush cooling cores in office-building thermal cavities that wayfind after dark without drawing on mains lighting. At 300 megapascals of compression the body can also act as a compressive wall element in this same register, not merely an infill. The caveat is double and heavy. Embodied CO₂ runs three and a quarter times higher than fired clay brick, and the cost of 47 euros per 200 g batch forbids bulk use entirely — this belongs as a signature trombe-wall insert, a ceremonial threshold plate, or a small-area accent, never as a full thermal mass volume. The samarium-praseodymium supply-chain score sits near 0.14, so specification has to be paid for by the dual capability, not by the heat storage alone.

Material character

At 7.86 g/cm³ in a 70×70×26 mm slab the weight lands firmly two-handed — dense for its footprint, closer in hand-feel to a structural stone offcut than to a ceramic tile. The body reads neutral grey with a faint warm cream undertone from the samarium-praseodymium content, visible only in side-light; the post-UV emission belongs in a companion shot with 365 nm excitation. Skin vitrified matte from the 1250 °C fire, edges cold-cut with diamond-saw kerf-whitening. Fully opaque. Against a zirconate sibling without the rare-earth pair the colour is slightly warmer and the sinter finer-grained, reading more closely to a stoneware surface than to a technical ceramic.

recipe

Recipe

200 g batch · peak 1250 °C
elementprecursorformulamasssafety
Prpraseodymium oxidePr6O116.98 gmoderate
Smsamarium oxideSm2O335.74 gmoderate
Sntin(IV) oxideSnO237.07 gsafe
Zrzirconium dioxideZrO220.21 gsafe
schedule
  • 1Ramp
  • 2Hold
  • 3Ramp
  • 4Ramp
  • 5Hold
  • 6Ramp
  • 7Ramp
watch for

UV-luminescent — emits visible light under 365 nm UV

Recipes are synthesis protocols for trained workshop use, with the full procedure, curves, and safety notes in the Recipe Atlas. Firing schedules are best estimates: the first firing of any composition is an experiment, not a production run.